Copper-Catalyzed S-Arylation of Thiols Using KF/Al2O3 [PDF]
Copper-catalyzed S-arylation of thiols can be accomplished using air-stable CuI as a copper source and 1,10-phenanthroline as a ligand in the presence of KF/Al2O3 as a suitable base.
Rahman Hosseinzadeh +3 more
doaj +1 more source
The direct 4-alkoxylation of 4-iodo-1H-pyrazoles with alcohols was achieved by a CuI-catalyzed coupling protocol. The optimal reaction conditions employed excess alcohol and potassium t-butoxide (2 equiv) in the presence of CuI (20 mol%) and 3,4,7,8 ...
Yoshihide Usami +10 more
doaj +1 more source
Multilabel Classification Models for the Prediction of Cross-Coupling Reaction Conditions
Machine-learned ranking models have been developed for the prediction of substrate-specific cross-coupling reaction conditions. Data sets of published reactions were curated for Suzuki, Negishi, and C-N couplings, as well as Pauson-Khand reactions ...
Michael R. Maser +5 more
semanticscholar +1 more source
Efficient Sonogashira Coupling Reaction Catalyzed by Copper (I) Iodide in the Presence of KF/Al2O3 [PDF]
We have developed a convenient and efficient method for coupling of aryl iodides and bromides with terminal alkynes. The protocol uses CuI as catalyst, 1, 10-phenanthroline as ligand, KF/Al2O3 as base and toluene as solvent.
Rahman Hosseinzadeh +2 more
doaj +1 more source
Simple Synthesis of Modafinil Derivatives and Their Anti-inflammatory Activity
Simple synthesis of modafinil derivatives and their biological activity are described. The key synthetic strategies involve substitution and coupling reactions. We determined the anti-inflammatory effects of modafinil derivatives in cultured BV2 cells by
Mankil Jung +5 more
doaj +1 more source
AbstractFor Abstract see ChemInform Abstract in Full Text.
Mecking, Stefan, Schlotterbeck, Ulf
openaire +2 more sources
Regioselective Formation of α-Vinylpyrroles from the Ruthenium-Catalyzed Coupling Reaction of Pyrroles and Terminal Alkynes Involving C–H Bond Activation [PDF]
The cationic ruthenium catalyst Ru3(CO)12/NH4PF6 was found to be highly effective for the intermolecular coupling reaction of pyrroles and terminal alkynes to give gem-selective α-vinylpyrroles.
Gao, Ruili, Yi, Chae S.
core +2 more sources
Investigation of the Pyridinium Ylide—Alkyne Cycloaddition as a Fluorogenic Coupling Reaction
The cycloaddition of pyridinium ylides with alkynes was investigated under mild conditions. A series of 13 pyridinium salts was prepared by alkylation of 4-substituted pyridines.
Simon Bonte +4 more
doaj +1 more source
Synthesis of 2-Acylphenol and Flavene Derivatives from the Ruthenium-Catalyzed Oxidative C-H Acylation of Phenols with Aldehydes [PDF]
The cationic ruthenium hydride complex [(C6H6)(PCy3)(CO)RuH]+BF4− has been found to be an effective catalyst for the oxidative C–H coupling reaction of phenols with aldehydes to give 2-acylphenol compounds.
Aponick +47 more
core +2 more sources
In-situ Nitrous Acid Generation over Silica Imidazole Catalyst for Dyes Production
The objective of this research is to prepare a new type of heterogeneous catalyst and to study its usage for in-situ nitrous acid generation to form a diazonium salt.
Kasim Mohammed Hello, Nahla Ghaze Fahad
doaj +1 more source

