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Suppressing the Excitonic Effect in Covalent Organic Frameworks for Metal-Free Hydrogen Generation [PDF]
[Image: see text] Photocatalytic hydrogen generation is a promising solution for renewable energy production and plays a role in achieving carbon neutrality.
Wang, Dong +3 more
core +1 more source
2.5-dimensional covalent organic frameworks
Covalently bonded crystalline substances with micropores have broad applications. Covalent organic frameworks (COFs) are representative of such substances. They have so far been classified into two-dimensional (2D) and three-dimensional (3D) COFs.
Tomoki Kitano +8 more
doaj +1 more source
Emerging experimental and computational methods for studying redox‐regulated structural transitions
Redox reactions can reshape proteins and alter how they behave in cells, with important consequences for health and disease. This review explores emerging experimental and computational approaches for discovering these redox‐sensitive protein switches, revealing their structural effects, and predicting their behavior, opening new opportunities to ...
Tasneem Rass +2 more
wiley +1 more source
Mycobacterial 3‐methylcrotonyl‐CoA carboxylase uses a mobile biotin‐carrying domain to shuttle a carboxyl group between two catalytic sites, enabling carboxylation of 3‐methylcrotonyl‐CoA during leucine breakdown. Cryo‐electron microscopy captures the carrier at both sites and reveals an inward loop movement that may prevent futile rebinding to the ...
Ajit Yadav +2 more
wiley +1 more source
The Shewanella oneidensis Fic enzyme SoFic targets the switch‐I region of EF‐Tu for AMPylation
Fic enzymes mediate diverse post‐translational modifications across all domains of life, including AMPylation. Prokaryotic EF‐Tu can be AMPylated and deAMPylated by the conserved Fic enzyme SoFic. Structural and biochemical approaches were used to characterize the effect of AMPylation on EF‐Tu, SoFic's enzymatic activities, and the enzyme‐target ...
Svenja Runge +6 more
wiley +1 more source
Pyrophosphonate Covalent Organic Frameworks [PDF]
Herein, we report a new family of covalent organic frameworks (COFs), namely pyrophosphonate-COFs, constructed via pyrophosphonate linkages. Pyrophosphonate-COFs can be synthesized via a single-step condensation reaction of the charge-assisted hydrogen ...
Xu, Ke +15 more
core +1 more source
Heterodimeric amino acid transporters consist of SLC7 and SLC3 family proteins arranged in a conserved structural organization. They regulate nutrient transport across cell membranes, supporting essential cellular functions. These transporters also contribute to xenobiotic/drug uptake and distribution.
Mariafrancesca Scalise +5 more
wiley +1 more source
Membrane composition and thermodynamic identity as boundaries of life for synthetic cell research
What makes a cell a cell? The boundary of a living cell is not just a wall. Read as a Markov blanket, the membrane separates internal from external states, generating identity and non‐equilibrium order. Can this identity be rebuilt from scratch in a synthetic cell?
Caterina Presutti, Bert Poolman
wiley +1 more source
Sub-stoichiometric 2D covalent organic frameworks from tri- and tetratopic linkers [PDF]
Covalent organic frameworks (COFs) are typically designed by breaking down the desired network into feasible building blocks - either simple and highly symmetric, or more convoluted and thus less symmetric.
Savasci, Goekcen +8 more
core +1 more source
Covalent Organic Frameworks: From Structures to Applications
Three-dimensional covalent organic frameworks possess hierarchical nanopores, enormous surface areas with high porosity, and open positions. The synthesis of large crystals of three-dimensional covalent organic frameworks is a challenge, since different ...
Quang Nhat Tran, Ngo Tran, Hyun Jong Lee
core +1 more source

