Rapid, Ambient Temperature Synthesis of Imine Covalent Organic Frameworks Catalyzed by Transition Metal Nitrates [PDF]
Covalent Organic Frameworks (COFs) are crystalline, porous organic materials with promise for applications including catalysis, energy storage, electronics, gas storage, water treatment, and drug delivery. Conventional solvothermal synthesis approaches
Dongyang, Zhu +7 more
core +1 more source
Enhancing Structural Control in Covalent Organic Frameworks through Steric Interaction-Driven Linker Design [PDF]
Covalent Organic Frameworks (COFs) exhibiting kagome (kgm) structures are promising crystalline porous materials with two distinct pores. However, the challenge arises from the potential formation of the polymorphic square-lattice (sql) structure, which ...
Panagiotis, Kastritis +5 more
core +1 more source
Metal-organic frameworks and covalent-organic frameworks in thermal transport
Understanding and modulating the inherently low thermal conductivity of crystalline porous frameworks is critical for their deployment in thermal-sensitive applications like gas storage, catalysis, and thermoelectrics.
Pengfei Xu +4 more
doaj +1 more source
The novel styrylquinazolinone‐based molecule W1B effectively suppresses glioblastoma by inhibiting IGF1R and EGFR. In high‐glucose microenvironments driving tumor resistance, W1B acts synergistically with the EGFR inhibitor dacomitinib. This combination safely blocks compensatory survival signaling in zebrafish xenograft models. Showcasing promising in
Patryk Rurka +9 more
wiley +1 more source
Amine-linked Covalent Organic Frameworks as a Powerful Platform for Post-Synthetic Modification: Structure Interconversion and Combined Linkage- and Pore-Wall-Modification [PDF]
Covalent organic frameworks have emerged as a powerful synthetic platform for installing and interconverting dedicated molecular functions on a crystalline polymeric backbone with atomic precision.
Igor, Moudrakovski +8 more
core +2 more sources
Thiophene-based covalent organic frameworks [PDF]
We report the synthesis and characterization of covalent organic frameworks (COFs) incorporating thiophene-based building blocks. We show that these are amenable to reticular synthesis, and that bent ditopic monomers, such as 2,5-thiophenediboronic acid, are defect-prone building blocks that are susceptible to synthetic variations ...
Bertrand, Guillaume +4 more
openaire +4 more sources
UiO‐66(Zr) metal–organic frameworks are chemically stable, biocompatible, and highly tunable nanomaterials. Their modular structure enables controlled drug delivery, multimodal bioimaging, and light‐activated photodynamic therapy, supporting integrated diagnostic and therapeutic (theranostic) applications in cancer and biomedical research.
Veronika Huntošová +2 more
wiley +1 more source
Thermomechanical properties of two-dimensional covalent organic frameworks studied by machine-learning molecular dynamics [PDF]
Two-dimensional (2D) covalent organic frameworks (COFs) are promising emerging 2D polymeric materials with broad applications such as adsorption, energy storage, and catalysis. However, their mechanical properties have not been systematically studied yet.
Bing, Wang, Jin, Zhang, Penghua, Ying
core +2 more sources
Reversible shape memory two-dimensional covalent organic frameworks
Two-dimensional covalent organic frameworks are a unique type of organic crystals with both weak layer-layer interaction and regular one-dimensional nanochannels.
Mingchao Shao +14 more
doaj +1 more source
Heterotropic regulation and negative homotropic cooperativity
We identified a structural module common to some proteins that couple negative cooperativity with heterotropic regulation, two features that rarely coexist. These proteins are ring‐like and present an ordered asymmetry whereby noncontacting subunits are symmetric, and their tertiary structure differs from that of contacting subunits.
Veronica Morea +5 more
wiley +1 more source

