Results 111 to 120 of about 5,641,250 (247)

Desulfonylative Functionalization of Organosulfones via Inert (Hetero)Aryl C(sp²)–SO₂ Bond Cleavage

Molecules
As “chemical chameleons,” organosulfones have been widely applied in various desulfonylative functionalization reactions. However, the desulfonylative functionalization of (hetero)arylsulfones through the cleavage of inert C(sp2)–SO2 bonds remains a ...
Rui Huang, Boning Gu, Ming Wang, Yinsong Zhao, Xuefeng Jiang   +4 more
doaj   +1 more source

Iron-catalysed cross-coupling of organolithium compounds with organic halides

Nature Communications, 2016
Cross coupling reactions of organolithiums are challenging due to their high reactivity, though palladium catalysed versions have been reported. Here, the authors report the cross coupling of organolithiums with aryl halides with inexpensive and widely ...
Zhenhua Jia, Qiang Liu, Xiao-Shui Peng, Henry N. C. Wong   +3 more
doaj   +1 more source

Revisiting Stability Criteria in Ball‐Milled High‐Entropy Alloys: Do Hume–Rothery and Thermodynamic Rules Equally Apply?

Advanced Engineering Materials, Volume 27, Issue 6, March 2025.
The stability criteria affecting the formation of high‐entropy alloys, particularly focusing in supersaturated solid solutions produced by mechanical alloying, are analyzed. Criteria based on Hume–Rothery rules are distinguished from those derived from thermodynamic relations. The formers are generally applicable to mechanically alloyed samples.
Javier S. Blázquez, Alejandro F. Manchón‐Gordón, Antonio Vidal‐Crespo, Rafael Caballero‐Flores, Jhon J. Ipus, Clara F. Conde   +5 more
wiley   +1 more source

A Simplified Laminar Flow Model for the Pultrusion of Glass Fiber/Polyethylene Terephthalate Commingled Yarns

Advanced Engineering Materials, EarlyView.
A simplified thermoplastic pultrusion model is developed to predict thermal fields in glass fiber/polyethylene terephthalate (GF/PET) composites with reduced computational cost. By combining effective material homogenization, validation against literature data, and Gaussian‐process‐based optimization, the study reveals how heating limits, pulling speed,
Elder Soares, Nadège Bouchonneau, Christian Jochum, Donald Radford   +3 more
wiley   +1 more source

Olefin-accelerated solid-state C–N cross-coupling reactions using mechanochemistry

Nature Communications, 2019
Cross-coupling reactions have been achieved in solution, yet tend to be inefficient in a solid state. Here, the authors report a solid-state palladium-catalyzed Buchwald-Hartwig cross-coupling using olefins as molecular dispersants, enabling reduction of
Koji Kubota, Tamae Seo, Katsumasa Koide, Yasuchika Hasegawa, Hajime Ito   +4 more
doaj   +1 more source

Modular Critical Element Recycling Platform Using a Nanoporous Additively Manufactured Gyroid

Advanced Engineering Materials, EarlyView.
A modular recycling platform integrates 3D‐printed nanoporous gyroid structures to enable efficient critical element recovery. This system utilizes a hierarchical architecture, combining macroscopic channels with polymerization‐induced nanoscale porosity. By systematically tuning structural wall thickness and resin formulation, the platform achieves an
Xiangyu Gao, Keldy Mason, Mert Gülçür, Rachel Paddock‐Lamb, Prince Alvin Fofanah, Zachariah A. Page, Michael Cullinan   +6 more
wiley   +1 more source

Workflow for Design of Experiments‐Based Modeling of Species Transport and Growth Kinetics in GaN Hydride Vapor Phase Epitaxy

Advanced Engineering Materials, EarlyView.
A novel workflow for investigating hydride vapor phase epitaxy for GaN bulk crystal growth is proposed. It combines Design of experiments (DoE) with physical simulations of mass transport and crystal growth kinetics, serving as an intermediate step between DoE and experiments.
J. Tomkovič, G. Lukin, H. Torkashvand, A. Kerschbaum, M. Müller, S. Besendörfer, J. Heitmann, J. Friedrich   +7 more
wiley   +1 more source

Fast, greener and scalable direct coupling of organolithium compounds with no additional solvents

Nature Communications, 2016
Cross-coupling reactions typically are carried out under dilute conditions of ethereal solvents. Here, the authors report a method for palladium catalysed cross-coupling of organolithium reagents that avoids the use of any added solvent with reaction ...
Erik B. Pinxterhuis, Massimo Giannerini, Valentín Hornillos, Ben L. Feringa   +3 more
doaj   +1 more source

Synthesis, Structure, and Reactivity of Palladium Proazaphosphatrane Complexes Invoked in C–N Cross-Coupling

, 2018
The preparation and reactivity of elusive palladium proazaphosphatrane complexes that represent putative intermediates in C–N cross-coupling reactions are described.
Nathan D. Schley, Gregory M. Gravalis, Nathan D. Schley (1863295), Adrian D. Matthews, Miles W. Johnson (2177464), Gregory M. Gravalis (5728556), Adrian D. Matthews (5728553), Miles W. Johnson   +7 more
core   +1 more source

Electrochemical Behavior of Flame‐Sprayed Sc‐Doped AlCoCrFeMo High‐Entropy Alloy Coatings in 3.5% Sodium Chloride Solution

Advanced Engineering Materials, EarlyView.
Scandium (Sc)‐doped AlCoCrFeMo HEA coatings are fabricated via flame spraying with 0.1, 0.3, and 0.5 wt% Sc additions. Among these, the HEA‐Sc0.3 coating exhibits the highest corrosion resistance, indicated by a more positive corrosion potential and lower current density.
Pankaj Kumar, Akash Vyas, Mohammad Aatif Qazi, Nashit Jalal, Maria Ophelia Jarligo, Mostafa Yakout, Jing Liu, André McDonald   +7 more
wiley   +1 more source