Highly Entangled Bottlebrush Polymer Networks
Bottlebrush polymers are difficult to entangle, enabling ultrasoft yet brittle networks. We report highly entangled bottlebrush elastomers that remain ultrasoft (∼1 kPa) yet stretch to ∼1800% and exhibit exceptional fatigue resistance. Their intrinsic fatigue strength—fatigue threshold normalized by modulus—surpasses that of highly entangled linear ...
Myoeum Kim +3 more
wiley +1 more source
A Molecular Dynamics Study of Crosslinked Phthalonitrile Polymers: The Effect of Crosslink Density on Thermomechanical and Dielectric Properties. [PDF]
Chua J, Tu Q.
europepmc +1 more source
Fully recombinant protein‐based biomaterials execute complex Boolean logic for user‐programmable material degradation and concomitant therapeutic cargo release. Biologics, such as growth factors, can be incorporated within the crosslinkers as “drugamers”, while encapsulated cells can be released according to nested YES/OR/AND‐type logical operations ...
Murial L. Ross +3 more
wiley +1 more source
A light‐responsive liquid crystal (LC) polymer network integrating molecular rotary motors and photothermal converters enables the decoupling of photochemical and photothermal effects. Selective wavelength activation allows orthogonal control over persistent shape encoding and fast reversible motion, enabling programmable soft robots capable of complex
Guiying Long +3 more
wiley +1 more source
Recycling of Polyurethanes via Covalent Adaptable Networks: The Role of Crosslink Density in Performance Recovery. [PDF]
Miravalle E +5 more
europepmc +1 more source
Frozen State of Sephadex® Gels of Different Crosslink Density Analyzed by X-ray Computed Tomography and X-ray Diffraction. [PDF]
Murase N +7 more
europepmc +1 more source
Meniscus‐Guided Interfacial Ring‐by‐Ring Assembly for In Situ Fabrication of Tubular Hydrogels
A tubular hydrogel fabrication method leveraging the meniscus effect at the oil‐water interface is presented. UV irradiation across the concave surface of the photocurable hydrogel precursor induces the formation of ring‐like hydrogel structures. Sequential ring‐by‐ring assembly within microchannels enables the construction of arteriole‐scale hydrogel ...
Yuki Kamiya +2 more
wiley +1 more source
Influence of Soft Segment Length and Crosslink Density on the Properties of Thermoreversible Diels-Alder Polyurethanes. [PDF]
Weise NK +6 more
europepmc +1 more source
Crosslink Density Is Reduced and Oxidation Is Increased in Retrieved Highly Crosslinked Polyethylene TKA Tibial Inserts. [PDF]
Liu T +3 more
europepmc +1 more source
Can Elastomers Combine Stiffness, Toughness and Fatigue Resistance?
This review studies how the molecular and macroscopic architecture of elastomers influence their mechanical properties including: stiffness, stretchability, toughness, fatigue resistance, and damping behavior. By linking the structure to performance, it proposes design principles for advanced elastomeric systems that combine mechanical properties ...
Eva Baur, Esther Amstad
wiley +1 more source

