Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV
Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse +4 more
wiley +1 more source
High-resolution UAV imagery-based instance segmentation for automatic counting of rubber trees across phenological seasons. [PDF]
Zeng J +5 more
europepmc +1 more source
Modulation of Epigenetic Control by Advanced Molecular Tweezers
Tailored dimeric molecular tweezers recognize the DNA‐binding part of Histone H4 and interrupt the essential histone‐DNA interaction. ABSTRACT This work addresses the question if supramolecular systems can be tailored to interfere with posttranslational modifications (PTM) and epigenetics.
My‐Hue‐Le +9 more
wiley +1 more source
Canopy Definitions Shape Canopy Space Filling-Productivity Relationships: Evidence From Terrestrial Laser Scanning. [PDF]
Ray T +7 more
europepmc +1 more source
N‐Boron‐Functionalized Anionic N‐Heterocyclic Carbenes (NBA‐NHCs)—A Case Study
The synthesis and characterization of a new family of N‐boron‐functionalized anionic N‐heterocyclic carbenes (NBA‐NHCs), IiPrB(CN)3−, IiPr(C2F5)BF2−, IMesB(CN)3−, and IMes(C2F5)BF2−, is reported. ABSTRACT The synthesis and characterization of a new family of N‐boron‐functionalized anionic NHCs (NBA‐NHCs), IiPrB(CN)3− (5), IiPr(C2F5)BF2− (6), IMesB(CN)3−
Sophie Mann +3 more
wiley +1 more source
A UAV RGB dataset and method for instance tree crown segmentation for biodiversity monitoring. [PDF]
Do MVH +10 more
europepmc +1 more source
Hydrogen‐release processes in silicon chemistry occur across a broad spectrum of systems, including crystalline silicon surfaces, nanoporous materials, Zintl phases, and molecular hydrides. This Review highlights how Si─H activation and H2 evolution are governed by structure, coordination environment, and dynamic access to reactive geometries, with ...
Robin Rothfelder, Jonathan O. Bauer
wiley +1 more source
Previous prescribed burns saved thousands of ancient sequoias during historically unprecedented wildfires. [PDF]
Dixon DJ +7 more
europepmc +1 more source
Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes
Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley +1 more source

