Results 11 to 20 of about 210,013 (270)

Direct synthetic routes to functionalised crown ethers. [PDF]

open access: yesOrg Chem Front, 2021
Crown ethers are macrocyclic hosts that can complex a wide range of inorganic and organic cations as well as neutral guest species. Their widespread utilization in several areas of fundamental and applied chemistry strongly relies on strategies for their
Nicoli F   +4 more
europepmc   +2 more sources

18-Crown-6 and Dibenzo-18-crown-6 Assisted Extraction of Cesium from Water into Room Temperature Ionic Liquids and Its Correlation with Stability Constants for Cesium Complexes

open access: yesMolecules, 2009
The pH-profiles of the extraction of Cs+ into four conventional (1-butyl-3-methylimidazolium hexafluorophosphate and bis[trifluoromethyl)sulphonyl]imides of 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, and 1-(2-ethylhexyl)-3 ...
Igor Vladimirovich Pletnev   +6 more
doaj   +1 more source

Towards ionic channels with crown ethers and calix[n]arenes (with n=6,8) [PDF]

open access: yes, 2006
This thesis reports the new crystal structures of crown ethers and calixarenes as well as the ionic conduction properties of crown ether channels. Chapter I gives general knowledge about ion channels.
Bergougnant, Remi
core   +1 more source

Synthesis and Coordination Chemistry of Ligands for Supramolecular Chemistry and Sensing Applications [PDF]

open access: yes
A series of multidentate N-donor ligands have been synthesised all containing pyridyl and pyridyl/thiazole units and their coordination behaviour is described.
Clayton, Hayley J.
core   +4 more sources

Komplexchemie von Molekülen mit hydrophilen und lipophilen Hohlräumen und Pseudohohlräumen

open access: yesCHIMIA, 1979
Molecules forming cavities suited for inclusion of ions or of neutral molecules are described: Open chain oligoethylene glycol ethers with and without rigid donor end groups are shown to complex alkali/alkaline earth metal ions and neutral molecules ...
Fritz Vögtle
doaj   +1 more source

Ab Initio Calculations on the Ground and Excited Electronic States of Thorium–Ammonia, Thorium–Aza-Crown, and Thorium–Crown Ether Complexes

open access: yesMolecules, 2023
Positively charged metal–ammonia complexes are known to host peripheral, diffuse electrons around their molecular skeleton. The resulting neutral species form materials known as expanded or liquid metals.
Zhongyuan Lu   +2 more
doaj   +1 more source

A Tutorial Mini-review on Crown Ethers Towards Rhodium Separation: Application of Crown Ether Studies

open access: yesES General, 2023
Metallic resources are generally obtained as raw materials from mines, and through a refining process, they are made into metallic materials. In recent years, however, the recovery of precious metals from so-called "urban mines," or waste, has become ...
Takashiro Akitsu   +4 more
doaj   +1 more source

LCST phase behavior of benzo-21-crown-7 with different alkyl chains

open access: yesBeilstein Journal of Organic Chemistry, 2019
The introduction of hydrophobic units into crown ethers can dramatically decrease the critical transition temperature of LCST and realize macroscopic phase separation at low to moderate temperature and concentration.
Yan Deng   +5 more
doaj   +1 more source

INTERACTION BETWEEN Li+ CATION WITH CROWN ETHERS OF Bz15C5, DBz16C5 AND DBz18C6: MOLECULAR MODELING BASE ON MNDO/d SEMIEMPIRICAL METHOD

open access: yesIndonesian Journal of Chemistry, 2010
The aim of this research is to find information about the substituent effect to the structure of crown ether benzo-15-crown-5 (Bz15C5), dibenzo-16-crown-5 (DBz16C5) and dibenzo-18-crown-6 (DBz18C6), and also crown ether selectivity to coordinate a Li ...
Harno Dwi Pranowo, Chairil Anwar
doaj   +1 more source

New crown-ether Dibenzo-18-crown-4 ligand via sequential one-pot reaction

open access: yesResults in Chemistry, 2021
A friendly synthetic rout for a new crown-ether was developed in this short communication. The method in question was able to produce the desirable product in high yields (up to 80%), even after some purification steps.
Rodolpho Alessandro Nesta Silva   +4 more
doaj   +1 more source

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