Results 111 to 120 of about 1,117,391 (197)
The role and use of Epichloë fungal endophytes in grazed temperate grass pastures and turf grasses are now well understood with regard to balancing pasture persistence while minimising animal health and welfare concerns. However, this understanding has only emerged since the early 1980s. Prior to this, although links between Epichloë endophytes, animal
John R. Caradus +2 more
wiley +1 more source
Bond dissociation energies (BDEs) of M+[c-(C2H4O)5] and M+[c-(C2H4O)6] for M = Na, K, Rb, and Cs are reported. The BDEs are determined experimentally by analysis of the thresholds for collision-induced dissociation of the cation−crown ether complexes by ...
Douglas Ray (3005466) +2 more
core +1 more source
Isodesmic Supramolecular Assembly of Phenylethynylene Bis‐Urea Macrocycles
A soluble phenylethynylene bis‐urea macrocycle assembles in polar media via an isodesmic hydrogen bonded mechanism. Spectroscopic and morphological studies reveal nanoscale aggregates with short chain length, while guest additives modulate enthalpy and polymerization, demonstrating tunable supramolecular assembly.
Fahidat A. Gbadamosi +5 more
wiley +1 more source
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino +1 more
wiley +1 more source
Characterization of microsolvated crown ethers from broadband rotational spectroscopy [PDF]
"Since they were first synthetized, crown ethers have been extensively used in organometallic chemistry due to their unparalleled binding selectivity with alkali metal cations.
Lopez, Juan Carlos
core
Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley +2 more sources
Hierarchical coordination engineering redistributes Li+ from anion‐dominated pairing toward polymer‐mediated binding. Strong primary sites promote salt dissociation, while distributed secondary sites sustain dynamic hopping pathways. This coordination landscape couples ion flux with polysulfide conversion, suppresses transport‐conversion decoupling ...
Zhong‐Wei Zheng +8 more
wiley +1 more source
The synthesis of crown ethers for selective chelation of alkali metal ions
Crown ethers of varying ring sizes have been used as selective chelators of radioactive alkali metal ions. The crown ethers capture cations with an ionic diameter fitted to their cavity size forming primarily 1:1 metal-crown ether complexes.
Shaojun Ren
core
Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source

