Results 111 to 120 of about 1,117,391 (197)

Early Contributions Leading to Understanding the Significance of Epichloë Endophyte in Temperate Grasses

open access: yesNew Zealand Journal of Agricultural Research, Volume 69, Issue 5, October 2026.
The role and use of Epichloë fungal endophytes in grazed temperate grass pastures and turf grasses are now well understood with regard to balancing pasture persistence while minimising animal health and welfare concerns. However, this understanding has only emerged since the early 1980s. Prior to this, although links between Epichloë endophytes, animal
John R. Caradus   +2 more
wiley   +1 more source

Intrinsic Affinities of Alkali Cations for 15-Crown-5 and 18-Crown-6:  Bond Dissociation Energies of Gas-Phase M+−Crown Ether Complexes

open access: yes, 2016
Bond dissociation energies (BDEs) of M+[c-(C2H4O)5] and M+[c-(C2H4O)6] for M = Na, K, Rb, and Cs are reported. The BDEs are determined experimentally by analysis of the thresholds for collision-induced dissociation of the cation−crown ether complexes by ...
Douglas Ray (3005466)   +2 more
core   +1 more source

Isodesmic Supramolecular Assembly of Phenylethynylene Bis‐Urea Macrocycles

open access: yesChemistry – A European Journal, Volume 32, Issue 34, 11 September 2026.
A soluble phenylethynylene bis‐urea macrocycle assembles in polar media via an isodesmic hydrogen bonded mechanism. Spectroscopic and morphological studies reveal nanoscale aggregates with short chain length, while guest additives modulate enthalpy and polymerization, demonstrating tunable supramolecular assembly.
Fahidat A. Gbadamosi   +5 more
wiley   +1 more source

Prism[5]MaxQ: A Sulfated Prism[5]Arene and Its Molecular Recognition Properties Toward a Panel of Quaternary Ammonium Guests

open access: yesChemistry – A European Journal, Volume 32, Issue 34, 11 September 2026.
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino   +1 more
wiley   +1 more source

Characterization of microsolvated crown ethers from broadband rotational spectroscopy [PDF]

open access: yes, 2016
"Since they were first synthetized, crown ethers have been extensively used in organometallic chemistry due to their unparalleled binding selectivity with alkali metal cations.
Lopez, Juan Carlos
core  

Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity

open access: yesAngewandte Chemie, Volume 138, Issue 36, 1 September 2026.
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley   +2 more sources

Hierarchical Primary‐Secondary Coordination Synchronizes Ion Flux and Sulfur Redox in Solid Polymer Electrolytes

open access: yesAdvanced Functional Materials, Volume 36, Issue 73, 10 September 2026.
Hierarchical coordination engineering redistributes Li+ from anion‐dominated pairing toward polymer‐mediated binding. Strong primary sites promote salt dissociation, while distributed secondary sites sustain dynamic hopping pathways. This coordination landscape couples ion flux with polysulfide conversion, suppresses transport‐conversion decoupling ...
Zhong‐Wei Zheng   +8 more
wiley   +1 more source

The synthesis of crown ethers for selective chelation of alkali metal ions

open access: yes, 1995
Crown ethers of varying ring sizes have been used as selective chelators of radioactive alkali metal ions. The crown ethers capture cations with an ionic diameter fitted to their cavity size forming primarily 1:1 metal-crown ether complexes.
Shaojun Ren
core  

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, Volume 38, Issue 51, 11 September 2026.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

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