Results 91 to 100 of about 71,246 (164)

Redox Biocatalysis in Lidocaine‐Based Hydrophobic Deep Eutectic Solvents: Non‐Conventional Media Outperform Aqueous Conditions

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Two hydrophobic DESs, lidocaine/oleic acid and lidocaine/decanoic acid, were utilized as reaction media that were enzyme‐compatible and highly substrate‐solubilizer for carbonyl reduction catalyzed by horse liver alcohol dehydrogenase, focusing on the effect of water contents and on maximizing substrate loadings, which showcases for the first time the ...
Ningning Zhang, Viktoria Lahmann, Jan Philipp Bittner, Pablo Domínguez de María, Sven Jakobtorweihen, Irina Smirnova, Selin Kara   +6 more
wiley   +1 more source

Advances in Electrocatalytic Valorization of Glycerol: From Fundamental Understanding to Practical Innovation

EcoEnergy, EarlyView.
This review provides a comprehensive overview of recent advances in glycerol electro‐oxidation reaction, covering electrocatalyst design, electrolyte and operating optimization, and mechanistic understanding of reaction pathways. Integrated anodic–cathodic systems and techno‐economic assessments are discussed, followed by key challenges and future ...
Jiamin Wang, Rafael B. Araujo, Hong Liu, Xiaowen Yu   +3 more
wiley   +1 more source

Insight Into the Origins of N2O Byproduct on Confinement Structure TiO2/MnSm Catalyst Through Sulfation Pre‐Treatment for Low‐Temperature NH3‐SCR Reaction

EcoEnergy, EarlyView.
Sulfation of TiO2 with tubular architecture assembly nanosheets cooperated with Sm modification endowed the TiO2–SO42−/MnSm catalyst with excellent low‐temperature NH3‐SCR activity, high N2 selectivity, and well H2O‐resistance. It clarifies how the Sm modification and sulfation adjusts the distribution of acid sites and modulates the activation of NH3 ...
Tian Zhao, Guodong Zhang, Xiaosheng Huang, Rongji Cui, Chao Feng, Zhicheng Tang   +5 more
wiley   +1 more source

Nonequilibrium Laser Regulation of the Electronic Structure of the Ni‐Based Electrode for Boosting Nucleophilic Electrooxidation of Alcohols

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work reports an efficient, simple, low‐cost, and scalable method for overall electrode preparation. Nonequilibrium laser synthesis rapidly yields NiO nanocrystals on which a nickel oxyhydroxide (NiOOH) overlayer is grown in situ. By varying the number of laser pulses, the Ni3+/Ni2+ ratio is precisely tuned, thereby modulating the electronic ...
Shilin Fan, Rongxia Zhao, Jianghuai Yuan, Zerui Li, Haotian Yang, Haoyun Sheng, Ran Zhang, Yuxiang Liu, Lin Li, Zhu Liu   +9 more
wiley   +1 more source

Support‐Driven Hydrogen Migration Enhances Ammonia Decomposition in Direct Ammonia Protonic Ceramic Fuel Cells

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Enhanced hydrogen species migration enabled by FN/BZY catalyst mitigates intermediate accumulation and improves DA‐PCFC performance during ammonia decomposition. Ammonia, with its high hydrogen density and carbon‐free nature, serves as ideal fuel for direct ammonia protonic ceramic fuel cells (DA‐PCFCs).
Meijuan Fei, Shuai Wang, Zhaohui Cai, Dongliang Liu, Cheng Huang, Xixi Wang, Jie Miao, Huangang Shi, Chuan Zhou, Wei Zhou   +9 more
wiley   +1 more source

Natural Anthraquinone‐Like Compound Extracted from Green Husk of Walnut Improves Photocatalytic H2O2 Production Catalyzed by TiO2 Nanoparticles

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this work, a novel biomolecule/semiconductor hybrid catalyst was prepared by loading anthraquinone‐liked juglone onto anatase TiO2. This catalyst exhibited high photocatalytic activity for H2O2 production. Hydrogen peroxide (H2O2) is a vital oxidant with broad industrial applications, and its production via photocatalysis represents a highly ...
Zengyin He, Cui Li, Mingze Ni, Shu Lin, Kezhen Qi   +4 more
wiley   +1 more source

1,2,6‐Thiadiazin‐4‐ones: Robust Photocatalysts for the Green Aerobic Oxidation of Sulfides to Sulfoxides

European Journal of Organic Chemistry, EarlyView.
A new photocatalyst for the aerobic photochemical oxidation of sulfides to sulfoxides is described under really low catalyst loading (0.01 mol%) and methanol as the green solvent. The chemoselective oxidation of sulfides to sulfoxides is accomplished using a new family of photocatalysts, namely 1,2,6‐thiadiazin‐4‐ones. Utilizing a low catalyst loading (
Charikleia I. Karaousta, Stamatis K. Serviou, Chrysanthi K. Spyropoulou, Nikolaos Stavridis, Andreas S. Kalogirou, Panayiotis A. Koutentis, Christoforos G. Kokotos   +6 more
wiley   +1 more source

Multiobjective Optimization of Hydrogen‐Assisted Calophyllum inophyllum Biodiesel Operation in a Compression Ignition Engine

Energy Science &Engineering, EarlyView.
Tri‐fuel diesel–Calophyllum inophyllum biodiesel–hydrogen operation was tested over 96 points in a diesel engine. Eight performance and emission metrics feed a preference‐agnostic Bootstrapped Empirical Multiobjective Ranking and Selection methodology, revealing load‐blend‐hydrogen windows that increase efficiency, restrain smoke, and expose NOx trade ...
C. Naga Kumar, Nageswara Rao Dayadi, J. M. Babu, Srinivasa Reddy Yarram, Ravikiran Chintalapudi, Bridjesh Pappula   +5 more
wiley   +1 more source

Contribution of Free Fatty Acids to Emulsion Building and Stability: Understanding the Mechanism From the Case Study of a Crude Red Palm Oil (Elaeis guineensis)—Based Emulsion Consumed in Africa and Known as Achu Soup/Sauce Jaune/Ncha

Food Chemistry International, EarlyView.
In an aqueous alkaline medium, fatty acids (from the hydrolysis of triglycerides or freely present in the oil) are ionised in order to form emulsifiers (carboxylates) which will physically stabilise the prepared emulsion. The higher the free fatty acids content of the oil and alkalinity of the solution, the higher will be the stability of the prepared ...
Ngoualem Kégah Franklin, Nguimbou Richard Marcel, Ndjouenkeu Robert, Asad Muhammad Khan   +3 more
wiley   +1 more source

Edible Antifungal Coatings Based on Litchi Chinensis Seed Starch Enriched With Pericarp Procyanidins for the Postharvest Preservation of Strawberries

Food Chemistry International, EarlyView.
Lychee starch coatings enriched with procyanidins showed strong antifungal activity and effectively preserved strawberry quality postharvest, reducing weight loss, decay, and senescence. This highlights their potential as a sustainable natural alternative for shelf‐life extension and fungal control in fresh produce.
Guillermo Castillo‐Olvera, José Sandoval‐Cortes, Juan A. Ascacio‐Valdes, Olga B. Álvarez‐Pérez, Jorge E. Wong‐Paz, María L. Flores López, Ahmet Yemenicioğlu, Cristóbal N. Aguilar   +7 more
wiley   +1 more source