Results 261 to 270 of about 491,196 (368)

Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals

open access: yesAngewandte Chemie, EarlyView.
PNP‐stabilized dinuclear [PdI]2 and [NiI]2 complexes with unsupported metal–metal bonds may serve as reservoir forms for homolytically generated metalloradical species, and a quantitative investigation of the metal–metal bond dissociation dynamics has been achieved.
Tim Bruckhoff   +4 more
wiley   +1 more source

Spatial Assembly of Mechanically Planar Chiral Rotaxanes on Rationally Designed Cavitands

open access: yesAngewandte Chemie, EarlyView.
A spatial molecular assembly strategy enables the synthesis of enantioenriched mechanically planar chiral rotaxanes. Inherently chiral cavitands are rationally designed to encode and transmit the stereochemical information. Predictable stereochemical induction is achieved by controlling the spatial arrangement of molecular components through ...
Liwen Xia   +3 more
wiley   +2 more sources

Time-resolved serial synchrotron and serial femtosecond crystallography of heme proteins using photocaged nitric oxide. [PDF]

open access: yesIUCrJ
Smyth P   +20 more
europepmc   +1 more source

De Novo Design of High‐Affinity Miniprotein Binders Targeting Francisella Tularensis Virulence Factor

open access: yesAngewandte Chemie, EarlyView.
Hybrid physics and deep‐learning enabled design methods identified miniprotein binders to Flpp3 (Francisella‐like lipoprotein), a key virulence factor from Francisella tularensis. Multiple candidates with nanomolar to picomolar binding affinities were obtained using yeast surface display screening and further experimental optimization.
Gizem Gokce‐Alpkilic   +18 more
wiley   +2 more sources

Reduction of Rare‐Earth Stannole Sandwich Complexes to Tin‐Based Radical Ligands and Tin–Tin Bonds

open access: yesAngewandte Chemie, EarlyView.
One‐electron reduction of dimetallic rare‐earth stannole complexes with KC8 produces a di‐tin radical ligand that shows strong coupling between tin and yttrium, gadolinium or dysprosium. Two‐electron reduction of the stannole complexes further populates a delocalized {M2Sn2} molecular orbital, enhancing the tin–tin bonding and simultaneously ...
Siddhartha De   +3 more
wiley   +2 more sources

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