Results 261 to 270 of about 485,962 (354)

Hochdrucksynthese eines stickstoffreichen Y(N5)3·N2 Pentazolats mit perowskitartiger Topologie

open access: yesAngewandte Chemie, EarlyView.
Yttriumpentazolat, Y(N5)3·N2, mit einem außergewöhnlich hohen Stickstoff‐Metall‐Verhältnis von 17:1 und Perowskit‐Topologie wurde aus Yttrium und Stickstoff bei 125 GPa und 3000 K in einer lasergeheizten Diamantstempelzelle synthetisiert.
Andrey Aslandukov   +8 more
wiley   +1 more source

Macromolecular crystallography at Elettra: current and future perspectives. [PDF]

open access: yesJ Synchrotron Radiat
Hegde RP   +13 more
europepmc   +1 more source

Hydrogen Bond‐Assisted PCET and Formation of WIII─OH in Bis(Dithiolene) Complex

open access: yesAngewandte Chemie, EarlyView.
The single crystal structure of complex [2Et3NH‐1] reveals hydrogen bonding at both W‐oxo and dithiolene‐S sites within the bis(dithiolene) WIV‐oxo complex. This finding provides critical evidence for dithiolene's involvement in proton reactions in high‐valent W‐oxo complexes.
Wonjung Lee   +9 more
wiley   +1 more source

Xanthopinacol Boronate: A Robust, Photochemically Assembled and Cleavable Boronic Ester for Orthogonal Chemistry

open access: yesAngewandte Chemie, EarlyView.
Xanthopinacol (xpin) boronates are a conceptually new class of masked boronic acids designed to alleviate many of the disadvantages of pinacol esters and other popular adducts. They can be formed directly from xanthone and UV light, undergo orthogonal transformations, and are cleavable under photoredox catalysis or oxidative conditions that recycle ...
David M. Heard   +2 more
wiley   +1 more source

Apo-state structure of the metabotropic glutamate receptor 5 transmembrane domain obtained using a photoswitchable ligand. [PDF]

open access: yesProtein Sci
Kondo Y   +15 more
europepmc   +1 more source

Asymmetric Intramolecular α‐Arylation of Polar Amino Acids Bearing β‐Leaving Groups

open access: yesAngewandte Chemie, EarlyView.
Use of enolate chemistry to functionalise amino acids with β‐heteroatom side‐chains (serine, cysteine, threonine, etc.) is hampered by β‐elimination. We show that α‐arylation can be achieved by incorporating the side chain into a saturated heterocycle, making the unwanted elimination a disfavoured 5‐endo‐trig reaction.
Ömer Taspinar   +6 more
wiley   +1 more source

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