Redox-dependent hydrogen-bond network rearrangement of ferredoxin-NADP<sup>+</sup> reductase revealed by high-resolution X-ray and neutron crystallography. [PDF]
Uenaka M+7 more
europepmc +1 more source
Rapid Access to an Enantioenriched Spiro Bisindole Directly from Indole and Acetone
A catalytic enantioselective one‐pot “self‐assembly” strategy was developed for the exceedingly convenient access to a spiro bisindole directly from indole and acetone. The obtained enantiopure C2‐symmetric bisindole showed exceptional performance as a chiral backbone of diverse effective catalysts or ligands. Abstract Disclosed here is a “one‐pot self‐
Jing‐Yi Wang+3 more
wiley +1 more source
An Atomically Dispersed Photocatalyst for Undirected para‐Selective C─H Bond Functionalizations
This study presents an atomically dispersed recyclable heterogeneous photocatalytic method for para‐selective trifluoromethylation of electron‐deficient arenes without directing groups. Unlike previous substrate‐dependent approaches, this recyclable, atomically dispersed photocatalyst enables scalable synthesis of bioactive trifluoromethylated ...
Suman Pradhan+16 more
wiley +1 more source
Current and future perspectives for structural biology at the Grenoble EPN campus: a comprehensive overview. [PDF]
McCarthy AA+27 more
europepmc +1 more source
Reactivity of a Methylene‐Bridged 1,3‐Bis(germylene) in Dynamic Equilibrium with Its Dimer
We report the properties and reactivity of an unprecedented methylene‐bridged 1,3‐bis(germylene) derivative. In the solid state, the 1,3‐bis(germylene) derivative undergoes dimerization to afford a 1,2,4,5‐tetragermacyclohexa‐1,4‐diene (Ge4CHD) derivative.
Daichi Uchida+5 more
wiley +1 more source
Transcription-Coupled Template Reconfiguration of 8-Oxoguanine for Error-Prone Transcription Revealed by Time-Resolved X-ray Crystallography and Molecular Dynamics. [PDF]
Oh J+5 more
europepmc +1 more source
Photoswitchable homo‐ and heterobimetallic helicates form with high diastereo‐ and regioselectivity via single‐step self‐assembly or self‐sorting. White‐light exposure autonomously operates one helicate as a molecular ratchet, promoting the selective formation of an out‐of‐equilibrium structure.
Maximilian J. Notheis+2 more
wiley +1 more source
Macromolecular crystallography at SPring-8 and SACLA. [PDF]
Yamamoto M, Kumasaka T.
europepmc +1 more source
Single‐crystal X‐ray diffraction analysis revealed a reduction‐induced ring cleavage with subsequent hydrogenation of a bilayer spironanographene upon treatment with alkali metals. Density Functional Theory (DFT) calculations suggested localized spin density on the C‐atom at the central spirocycle upon one‐fold reduction, facilitating a site‐specific ...
Juan Lión‐Villar+7 more
wiley +1 more source
The current status and future prospects of the Synchrotron Radiation Protein Crystallography Core Facility at NSRRC: a focus on the TPS 05A, TPS 07A and TLS 15A1 beamlines. [PDF]
Chou CK+7 more
europepmc +1 more source