Results 271 to 280 of about 485,962 (354)

Rapid Access to an Enantioenriched Spiro Bisindole Directly from Indole and Acetone

open access: yesAngewandte Chemie, EarlyView.
A catalytic enantioselective one‐pot “self‐assembly” strategy was developed for the exceedingly convenient access to a spiro bisindole directly from indole and acetone. The obtained enantiopure C2‐symmetric bisindole showed exceptional performance as a chiral backbone of diverse effective catalysts or ligands. Abstract Disclosed here is a “one‐pot self‐
Jing‐Yi Wang   +3 more
wiley   +1 more source

An Atomically Dispersed Photocatalyst for Undirected para‐Selective C─H Bond Functionalizations

open access: yesAngewandte Chemie, EarlyView.
This study presents an atomically dispersed recyclable heterogeneous photocatalytic method for para‐selective trifluoromethylation of electron‐deficient arenes without directing groups. Unlike previous substrate‐dependent approaches, this recyclable, atomically dispersed photocatalyst enables scalable synthesis of bioactive trifluoromethylated ...
Suman Pradhan   +16 more
wiley   +1 more source

Current and future perspectives for structural biology at the Grenoble EPN campus: a comprehensive overview. [PDF]

open access: yesJ Synchrotron Radiat
McCarthy AA   +27 more
europepmc   +1 more source

Reactivity of a Methylene‐Bridged 1,3‐Bis(germylene) in Dynamic Equilibrium with Its Dimer

open access: yesAngewandte Chemie, EarlyView.
We report the properties and reactivity of an unprecedented methylene‐bridged 1,3‐bis(germylene) derivative. In the solid state, the 1,3‐bis(germylene) derivative undergoes dimerization to afford a 1,2,4,5‐tetragermacyclohexa‐1,4‐diene (Ge4CHD) derivative.
Daichi Uchida   +5 more
wiley   +1 more source

Light‐Driven Ratchet Mechanism Accelerates Regioselective Metal‐Cation Exchange in a Heterobimetallic Helicate

open access: yesAngewandte Chemie, EarlyView.
Photoswitchable homo‐ and heterobimetallic helicates form with high diastereo‐ and regioselectivity via single‐step self‐assembly or self‐sorting. White‐light exposure autonomously operates one helicate as a molecular ratchet, promoting the selective formation of an out‐of‐equilibrium structure.
Maximilian J. Notheis   +2 more
wiley   +1 more source

Macromolecular crystallography at SPring-8 and SACLA. [PDF]

open access: yesJ Synchrotron Radiat
Yamamoto M, Kumasaka T.
europepmc   +1 more source

Reduction‐Induced C─C Cleavage and Site‐Specific Hydrogenation of a Highly Strained Bilayer Spironanographene

open access: yesAngewandte Chemie, EarlyView.
Single‐crystal X‐ray diffraction analysis revealed a reduction‐induced ring cleavage with subsequent hydrogenation of a bilayer spironanographene upon treatment with alkali metals. Density Functional Theory (DFT) calculations suggested localized spin density on the C‐atom at the central spirocycle upon one‐fold reduction, facilitating a site‐specific ...
Juan Lión‐Villar   +7 more
wiley   +1 more source

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