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Facile synthesis of Cu2ZnSnS4 nanocrystals
CrystEngComm, 2011A facile, greener and inexpensive method was developed to synthesize high quality quarternary Cu2ZnSnS4 (CZTS) nanocrystals at temperature lower than 220 °C, in which Cu2ZnSn(S2CNEt2)10, oleylamine and oleic acid were used as the precursor, activation agent and capping agent, respectively.
Chao Zou +7 more
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Electrodeposition of thin Cu2ZnSnS4 films
Russian Journal of Electrochemistry, 2017The electrochemical behavior of copper(II), zinc(II), and thiosulfate (S2O3 2-) ions on the molybdenum electrode in individual 0.2 М sodium sulfate solutions (рН 6.7) and with addition of either 0.1 М tartaric acid (рН 4.6) or 0.1 М citric acid (рН 4.7) is studied.
M. B. Dergacheva +2 more
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Sprayed films of stannite Cu2ZnSnS4
Applied Surface Science, 1996Abstract A stoichiometric Cu2ZnSnS4 film with the stannite structure and resistivity of 2 × 10 2 Ω · cm has been prepared by annealing polycrystalline quaternary films at 550°C, which are spray-deposited on glass substrates, in an argon gas flow containing H2S.
Norio Nakayama, Kentaro Ito
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Microphotoluminescence study of Cu2ZnSnS4 polycrystals
Journal of Photonics for Energy, 2013Microphotoluminescence studies of Cu 2 ZnSnS 4 polycrystals were performed. At room temperature, two photoluminescence (PL) bands were detected at 1.39 and 1.53 eV and attributed to band-to-tail (BT) and band-to-band (BB) recombination, respectively. At lower temperatures, band-to-impurity recombination always dominates.
Maarja Grossberg +3 more
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Improvement of Mo/Cu2ZnSnS4 interface for Cu2ZnSnS4 (CZTS) thin film solar cell application
MRS Proceedings, 2014ABSTRACTThe focus of this work is on back contact improvement for sputtered CZTS thin film solar cells. Three methods have been investigated including a thin Ag coating, a thin ZnO coating on the Mo back contact and rapid thermal annealing of the back contact.
Hongtao Cui +8 more
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Synthesis and characterization of Cu2ZnSnS4 nanoparticles
Nanomaterials and Energy, 2015Copper zinc tin sulfide (Cu2ZnSnS4 or CZTS) is a p-type semiconducting material with high absorption coefficient (104 cm−1) and a band gap of ~1·5 eV. Most of its constituents are earth abundant and are environmentally benign. Therefore, in this work, the authors investigated structural and optical properties of CZTS nanoparticles synthesized by ...
Annapoornam Ganesan Kannan +1 more
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Wurtzite Cu2ZnSnS4 nanocrystals: a novel quaternary semiconductor
Chemical Communications, 2011A new wurtzite phase Cu(2)ZnSnS(4) was discovered and the corresponding nanocrystals have been successfully synthesized. They have been characterized in detail and showed the photoelectric response, which demonstrated their potential in the application of photovoltaic devices.
Xiaotang, Lu +3 more
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Size control and quantum confinement in Cu2ZnSnS4 nanocrystals
Chemical Communications, 2011Starting with metal dithiocarbamate complexes, we synthesize colloidal Cu(2)ZnSnS(4) (CZTS) nanocrystals with diameters ranging from 2 to 7 nm. Structural and Raman scattering data confirm that CZTS is obtained rather than other possible material phases. The optical absorption spectra of nanocrystals with diameters less than 3 nm show a shift to higher
Ankur, Khare +4 more
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Nanostructured thermoelectric kesterite Cu2ZnSnS4
2021To support the growing global demand for energy, new sustainable solutions are needed both economically and environmentally. Thermoelectric waste heat recovery and energy harvesting could contribute by increasing industrial process efficiency, as well as powering stand-alone devices, microgenerators, and small body appliances.The structural complexity ...
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Cu2ZnSnS4 nanocrystals and graphene quantum dots for photovoltaics
Nanoscale, 2011Semiconductor quantum dots exhibit great potential for applications in next generation high efficiency, low cost solar cells because of their unique optoelectronic properties. Cu(2)ZnSnS(4) (CZTS) nanocrystals and graphene quantum dots (GQDs) have recently received much attention as building blocks for use in solar energy conversion due to their ...
Jun, Wang, Xukai, Xin, Zhiqun, Lin
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