Results 181 to 190 of about 60,004 (256)

Synthesis and Characterization of π‐Extended Azulenes via Nucleophilic Substitution and Intramolecular Cyclization of 5‐Alkynyl‐6‐Fluoroazulenes

open access: yesChemistryEurope, EarlyView.
A modular synthetic approach enables the preparation of azulene‐fused heterocycles via nucleophilic aromatic substitution followed by intramolecular cyclization of alkynyl fluoroazulenes. The method allows the incorporation of various heteroatoms (N, O, S, Se, and Te), leading to structurally diverse heteroannulated azulenes.
Martin C. Dietl   +8 more
wiley   +1 more source

Uncertainty as a driving force. [PDF]

open access: yesTidsskr Nor Laegeforen
Heier I, Nerli TF, Damskog IG, Han PKJ.
europepmc   +1 more source

Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications

open access: yesChemistryEurope, EarlyView.
This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang   +6 more
wiley   +1 more source

KI‐Doped α‐Mo2C Stably Catalyze Near‐Equilibrium CO2 to CO Beyond 1000 Hours

open access: yesCarbon Energy, EarlyView.
Through iodine doping and effective stabilization of surface oxygen content, KI‐doped α‐Mo2C achieves a sustained equilibrium yield ratio of 0.95 over 1000 h at 400°C and 4 bar in reverse water–gas shift (RWGS) reaction. Furthermore, the catalyst has been successfully scaled up to the kilogram level, indicating considerable potential for industrial ...
Haipeng Wang   +6 more
wiley   +1 more source

Next Generation Hosts for Protein Recognition, Assembly and More

open access: yesChemistry – A European Journal, EarlyView.
The original design of synthetic receptors for proteins was based on macrocycles with a hydrophobic core and a polar/charged periphery. This design, geared towards protein recognition, facilitates receptor self‐assembly. Macrocycle oligomerization, in turn, contributes to protein assembly as evidenced in many cocrystal structures.
Peter B. Crowley
wiley   +1 more source

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

open access: yesChemistry – A European Journal, EarlyView.
Staggered, square, and heavily bent dimers occur in the five known solvatomorphs of paddlewheel (PW) complex [PtVO(SOCPh)4]. These and other structural motifs are well within energetic reach due to the shallow potential energy surface that guides dimerization and are included in a revised classification of available structural data on heterobimetallic ...
Olga Mironova   +3 more
wiley   +1 more source

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