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Five-Membered Cyclic Carbonates: Versatility for Applications in Organic Synthesis, Pharmaceutical, and Materials Sciences

open access: yesApplied Sciences, 2021
This review presents the recent advances involving several applications of five-membered cyclic carbonates and derivatives. With more than 150 references, it covers the period from 2012 to 2020, with special emphasis on the use of five-membered cyclic ...
Patrick Rollin   +6 more
doaj   +4 more sources

Efficient and Reusable Iron Catalyst to Convert CO2 into Valuable Cyclic Carbonates [PDF]

open access: yesMolecules, 2021
The production of cyclic carbonates from CO2 cycloaddition to epoxides, using the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = 1H-pyrazol-1-yl) as a catalyst, is achieved in excellent yields (up to 98%) in a tailor-made ionic liquid (IL ...
Ana P. C. Ribeiro   +2 more
doaj   +2 more sources

The Application of Biomass-Based Catalytic Materials in the Synthesis of Cyclic Carbonates from CO2 and Epoxides [PDF]

open access: yesMolecules, 2020
The synthesis of cyclic carbonates from carbon dioxide (CO2) and epoxides is a 100% atom economical reaction and an attractive pathway for CO2 utilisation.
Li Guo   +8 more
doaj   +2 more sources

An Update of Transition Metal-Catalyzed Decarboxylative Transformations of Cyclic Carbonates and Carbamates [PDF]

open access: yesMolecules, 2019
Functionalized cyclic organic carbonates and carbamates are frequently used in a number of transition metal-catalyzed decarboxylative reactions for the construction of interesting molecules.
Linhong Zuo   +3 more
doaj   +2 more sources

One-pot synthesis of oxazolidinones and five-membered cyclic carbonates from epoxides and chlorosulfonyl isocyanate: theoretical evidence for an asynchronous concerted pathway [PDF]

open access: yesBeilstein Journal of Organic Chemistry, 2020
The one-pot reaction of chlorosulfonyl isocyanate (CSI) with epoxides having phenyl, benzyl and fused cyclic alkyl groups in different solvents under mild reaction conditions without additives and catalysts was studied.
Esra Demir   +5 more
doaj   +2 more sources

Novel and highly efficient electro-catalytic cycloaddition of CO2 and epoxides to cyclic carbonates over reusable ionic liquid-based cooperative catalytic system

open access: yesGreen Chemistry Letters and Reviews, 2023
A novel and highly efficient electro-catalytic protocol for the synthesis of cyclic carbonates from epoxides and CO2 using 1-aminopropyl-3-methylimidazolium dicyanamide ([APMIm]DCA) as the supporting electrolyte, graphite as the anode, and Ti/TiO2-CNT-Pt
Yu Lin Hu, Xiao Bing Liu, Qi Rong
doaj   +1 more source

Application of Covalent Organic Frameworks (COFs) in Cyclic Carbonate Production using a Green Method: An Overview

open access: yesMaterials Proceedings, 2023
One of the strategies suggested for solving the greenhouse gas problem is the transformation of CO2 into valuable chemicals, such as carbamates, cyclic carbonates, oxazolidones and tetramic acids.
Gamze Ozcakir
doaj   +1 more source

Electrosynthesis of Cyclic Carbonates from CO2 and Epoxides on Compacted Silver Nanoparticles Electrode

open access: yesInternational Journal of Electrochemical Science, 2017
Electrosynthesis of cyclic carbonates from carbon dioxide with epoxides has been carried out at room temperature and normal pressure in a one-compartment electrochemical cell using silver nanoparticles electrode as cathode, avoiding any additional ...
La-Xia Wu   +5 more
doaj   +1 more source

Synthesis of glycerol carbonate from glycerin with CaCO3 in a batch reactor

open access: yesDesigned Monomers and Polymers, 2022
In the present work, a reaction methodology was implemented using a batch reactor, which synthesized glycerol carbonate (GC) using glycerin and CaCO3. A crystallographic analysis of CaCO3 was performed to determine its crystalline form.
Ana Beatriz Morales Cepeda   +4 more
doaj   +1 more source

Catalytic Conversion of Carbon Dioxide by Metal-Organic Frameworks: an Effective Approach for CO2 Utilization [PDF]

open access: yesPollution, 2023
Due to the increase in carbon dioxide emission, there is a need for achieving efficient ways to reduce CO2 harmful effects. There are several strategies to mitigate atmospheric CO2 concentration.
Leila Tayebi   +2 more
doaj   +1 more source

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