Microemulsion breakdown by pervaporation technique: Effect of the alkyl chain length of n-alkanol, a cosurfactant of the microemulsion [PDF]
Two sets of microemulsions, cyclohexane- and water-rich ones, were prepared with the following n-alkanols as cosurfactants: n-propanol, n-butanol, n-pentanol, and n-hexanol.
Canselier, Jean-Paul +2 more
core +1 more source
Liquid crystalline properties of unsymmetrically substituted phthalocyanines: structural features leading to nematic mesophase materials [PDF]
A novel homologous series of four 1,4,8,11,15,18-hexakis(pentyl)-22-methyl-25-hydroxyalkylphthalocyanine derivatives with the hydroxyalkyl chain varying from hydroxynonyl through to hydroxydodecyl has been synthesized to investigate the role of the ...
Bryant, Geoffrey +4 more
core +1 more source
(E)-1,1′-(Diazene-1,2-diyl)bis(cyclohexane-1-carbonitrile)
The whole molecule of the title compound, C14H20N4, is generated by inversion symmetry. The mid-point of the N=N bond is situated on the inversion centre. The conformation about this central N=N bond is E.
Farzana Begum +2 more
doaj +1 more source
Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Desrat, S, van de Weghe, P
core +1 more source
Experimental fenceline sensor pods (SPods) fitted with 30 s duration canister grab sampling (CGS) systems were deployed at a site near chemical facilities in Louisville, KY, from 4 June 2018 to 5 January 2020.
Megan MacDonald +3 more
doaj +1 more source
The Radiolysis of Cyclohexane. IV. The Effect of Solutes on the Radiolysis of Liquid Cyclohexane
The effect of the addition of vanlous solutes, such as iodine, aromatic and olefinic compounds, and acetylene, on the gamma radiolysis of liquid cyclohexane was investigated by measuring the yield of hydrogen and in some cases those of hydrogenated compounds of the solutes.
Kiyoaki Kikuchi, Shin Sato, Shōji Shida
openalex +4 more sources
Influence of Dielectric Environment upon Isotope Effects onGlycoside Heterolysis: Computational Evaluation and AtomicHessian Analysis [PDF]
Isotope effects depend upon the polarity of the bulk medium in which a chemical process occurs. Implicit solvent calculations with molecule-shaped cavities show that the equilibrium isotope effect (EIE) for heterolysis of the glycosidic bonds in 5 ...
Porter, Alexander J. +3 more
core +1 more source
Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol
In the title compound, C9H16O4, the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å.
Takeshi Oishi +7 more
doaj +1 more source
Liquid insulation is used in high voltage equipment such as power transformers as both dielectric medium and coolant. Breakdown in liquid insulation tends to be governed either by streamer initiation under more uniform fields, or by streamer propagation ...
Carl P. Wolmarans +4 more
doaj +1 more source
Structure and mobility of cyclohexane as a solvent for Trans-Polyisoprene
Solutions of {\it trans}$-$polyisoprene in cyclohexane are investigated in atomistic detail at different compositions at two different temperatures. We investigate the influence of polymer concentration on the dynamics of the solvent molecules and the ...
Faller, Roland
core +1 more source

