Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate [PDF]
Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics.
Bercaw, John E. +2 more
core
A minimally invasive, transepithelial corneal cross‐linking (TE‐CXL) approach is presented using upconversion nanoparticles (UCNPs)‐loaded contact lenses (UCLs), after topical delivery of hyaluronate–riboflavin conjugates. The NIR‐to‐UV/blue light conversion by UCNPs in a UCL can activate riboflavin for TE‐CXL, resulting in the biomechanical strength ...
Gibum Lee +8 more
wiley +1 more source
Oxidation of Cyclohexane to Cylohexanol and Cyclohexanone Over H4[a-SiW12O40]/TiO2 Catalyst
Oxidation of cyclohexane to cyclohexanol and cyclohexanone was carried out using H4[a-SiW12O40]/TiO2 as catalyst. In the first experiment, catalyst H4[a-SiW12O40]/TiO2 was synthesized and characterized using FTIR spectroscopy and X-Ray analysis.
Aldes Lesbani +4 more
doaj +1 more source
Antitumor Profile of Carbon-Bridged Steroids (CBS) and Triterpenoids
This review focuses on the rare group of carbon-bridged steroids (CBS) and triterpenoids found in various natural sources such as green, yellow-green, and red algae, marine sponges, soft corals, ascidians, starfish, and other marine invertebrates.
Valery M. Dembitsky +2 more
doaj +1 more source
Universal Ratios of Characteristic Lengths in Semidilute Polymer Solutions
We use experimental and simulation data from the literature to infer five characteristic lengths, denoted $\xi_s$, $\xi_f$, $\xi_\Pi$, $\xi_\phi$, and $\xi_D$ of a semidilute polymer solution.
Huang, Jung-Ren, Witten, T. A.
core +3 more sources
Liquid crystalline properties of unsymmetrically substituted phthalocyanines: structural features leading to nematic mesophase materials [PDF]
A novel homologous series of four 1,4,8,11,15,18-hexakis(pentyl)-22-methyl-25-hydroxyalkylphthalocyanine derivatives with the hydroxyalkyl chain varying from hydroxynonyl through to hydroxydodecyl has been synthesized to investigate the role of the ...
Bryant, Geoffrey +4 more
core +1 more source
Electroactive Liquid Crystal Elastomers as Soft Actuators
Electroactive liquid crystal elastomers (eLCEs) can be actuated via electromechanical, electrochemical, or electrothermal effects. a) Electromechanical effects include Maxwell stress, electrostriction, and the electroclinic effect. b) Electrochemical effects arise from electrode redox reactions.
Yakui Deng, Min‐Hui Li
wiley +1 more source
Trispyrazolylborate Ligands Supported on Vinyl Addition Polynorbornenes and Their Copper Derivatives as Recyclable Catalysts [PDF]
Polynorbornenes prepared by vinyl addition poly- merization and bearing pendant alkenyl groups serve as skeletons to support trispyrazolylborate ligands (Tpx) built at those alkenyl sites.
Albéniz Jiménez, Ana Carmen +6 more
core +2 more sources
Photo‐Switching Thermal and Lithium‐Ion Conductivity in Azobenzene Polymers
Light‐responsive azobenzene polymers control thermal and ionic transport simultaneously through structural transitions. UV illumination disrupts π–π stacking, converting crystalline trans states to amorphous cis configurations. Thermal conductivity drops from 0.45 to 0.15 W·m−1·K−1 while Li+ diffusivity increases 100 fold. This dual transport switching
Jaeuk Sung +7 more
wiley +1 more source
Construction of a Chemical Kinetic Model of Five-Component Gasoline Surrogates under Lean Conditions
The requirements for improving the efficiency of internal combustion engines and reducing emissions have promoted the development of new combustion technologies under extreme operating conditions (e.g., lean combustion), and the ignition and combustion ...
Chao Yang, Zhaolei Zheng
doaj +1 more source

