Experimental fenceline sensor pods (SPods) fitted with 30 s duration canister grab sampling (CGS) systems were deployed at a site near chemical facilities in Louisville, KY, from 4 June 2018 to 5 January 2020.
Megan MacDonald+3 more
doaj +1 more source
Influence of Dielectric Environment upon Isotope Effects onGlycoside Heterolysis: Computational Evaluation and AtomicHessian Analysis [PDF]
Isotope effects depend upon the polarity of the bulk medium in which a chemical process occurs. Implicit solvent calculations with molecule-shaped cavities show that the equilibrium isotope effect (EIE) for heterolysis of the glycosidic bonds in 5 ...
Porter, Alexander J.+3 more
core +1 more source
Crystal structure of (±)-(5SR,6SR)-6-ethenyl-1-[(RS)-1-phenylethoxy]-1-azaspiro[4.5]decan-2-one
In the title compound, C19H25NO2, the pyrrolidine ring adopts an envelope form, with the spiro C atom as the flap, while the cyclohexane ring shows a chair form. A weak intramolecular C—H...O interaction supports the molecular conformation, generating an
Takeshi Oishi+5 more
doaj +1 more source
Liquid insulation is used in high voltage equipment such as power transformers as both dielectric medium and coolant. Breakdown in liquid insulation tends to be governed either by streamer initiation under more uniform fields, or by streamer propagation ...
Carl P. Wolmarans+4 more
doaj +1 more source
Structure and mobility of cyclohexane as a solvent for Trans-Polyisoprene
Solutions of {\it trans}$-$polyisoprene in cyclohexane are investigated in atomistic detail at different compositions at two different temperatures. We investigate the influence of polymer concentration on the dynamics of the solvent molecules and the ...
Faller, Roland
core +1 more source
Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]
We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Desrat, S, van de Weghe, P
core +1 more source
Phase Equilibria in the Systems Acetone–Methanol, Acetone–Cyclohexane, Methanol–Cyclohexane, and Acetone–Methanol–Cyclohexane [PDF]
The vapor pressure and vapor composition of the methanol–cyclohexane system were investigated at temperatures ranging from 25 to 50°. The same properties of the binary systems: acetone–methanol and acetone–cyclohexane, as well as those of the ternary system: methanol–cyclohexane–acetone, were determined experimentally at 25°.
A. N. Campbell, S. C. Anand
openaire +2 more sources
This paper presents the results of investigations on the removal of cyclohexane vapors from air using a peat-perlite packed biotrickling filter. Effects of basic process parameters i.e.
P. Rybarczyk+3 more
semanticscholar +1 more source
Determination of polycyclic aromatic hydrocarbons in tea infusions samples by high performance liquid chromatography with fluorimetric detection [PDF]
This study focuses on the contamination of 15 polycyclic aromatic hydrocarbons (PAHs) , recommended by the US Environmental Protection Agency, in 10 tea brands distributed in Italy.
Apriceno, Azzurra+3 more
core +1 more source
Calculating Partition Coefficients of Small Molecules in Octanol/Water and Cyclohexane/Water.
Partition coefficients describe how a solute is distributed between two immiscible solvents. They are used in drug design as a measure of a solute's hydrophobicity and a proxy for its membrane permeability.
Caitlin C. Bannan+3 more
semanticscholar +1 more source