Results 61 to 70 of about 122,535 (318)

Influence of Dielectric Environment upon Isotope Effects onGlycoside Heterolysis: Computational Evaluation and AtomicHessian Analysis [PDF]

open access: yes, 2019
Isotope effects depend upon the polarity of the bulk medium in which a chemical process occurs. Implicit solvent calculations with molecule-shaped cavities show that the equilibrium isotope effect (EIE) for heterolysis of the glycosidic bonds in 5 ...
Porter, Alexander J.   +3 more
core   +1 more source

Mechanotransducing Organic Electrochemical Diode for Crosstalk‐Inhibited Artificial Skin

open access: yesAdvanced Functional Materials, EarlyView.
An innovative approach is presented to a stretchable mechanotransducing diode that unifies rectification and tactile‐sensing functionality. This approach enables to fabricate the diode that maintains a large rectification ratio (5 × 102) at a high operational frequency (100 Hz).
Taeyeong Kim   +7 more
wiley   +1 more source

The choice of possible entrainers for the extractive distillation of binary mixture benzene – cyclohexane

open access: yesТонкие химические технологии, 2011
The approaches to the formation of a set of possible entrainers for extractive distillation of the binary mixture benzene - cyclohexane are considered. The approaches are based on the analyses of concentration dependence of different excess thermodynamic
V. M. Raeva   +3 more
doaj  

INTENSIFICATION OF THE CYCLOHEXANE LIQUID PHASE OXIDATION PROCESS

open access: yesТонкие химические технологии, 2018
Liquid-phase oxidation of cyclohexane to cyclohexanol and cyclohexanone was studied in the absence of solvents under an air pressure of 0.5-5 MPa, in the temperature range 115-150 °C, catalyzed by N-hydroxyphthalimide (N-HPI).
A. S. Frolov   +5 more
doaj   +1 more source

Using the Photostationary State of Arylazopyrazoles to Control Phase Transitions of Liquid Crystals

open access: yesAdvanced Functional Materials, EarlyView.
A series of new arylazopyrazole photoswitches is designed as dopants for liquid crystalline materials. Unprecedented, the distribution of photoisomers at the photostationary state upon irradiation with light of specific wavelengths (365, 460, 520 nm) is used to control the liquid crystalline phase transitions under isothermal conditions, including ...
Tobias Thiele   +3 more
wiley   +1 more source

Cyclohexane plastic phase I: single-crystal diffraction images and new structural model

open access: yesIUCrData, 2023
The plastic phase of cyclohexane (polymorph I) was studied by Kahn and co-workers, without achieving a satisfactory determination of the atomic coordinates [Kahn et al. (1973). Acta Cryst. B29, 131–138].
Sylvain Bernès, Sebastian Camargo
doaj   +1 more source

Photophysics and Inverted Solvatochromism of 7,7,8,8-Tetracyanoquinodimethane (TCNQ) [PDF]

open access: yes, 2019
We report the absorption, fluorescence, and Raman spectroscopy of 7,7,8,8- tetracyanoquinodimethane (TCNQ) in a variety of solvents. The fluorescence quantum yields (QYs) of linear alkane solutions are similar to one another, but QY is shown to acutely ...
IIMORI Toshifumi   +4 more
core   +2 more sources

Overcoming the Stability Issue for Hydrophobic Hole Transporting Layers Utilized in Tin‐Lead Perovskite and Tandem Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
A non‐annealed process is developed for non‐PEDOT:PSS inverted tin‐lead perovskite solar cells to attain PCE 22.67% for the PTAA‐based device. When PTAA is applied in an all‐perovskite tandem solar cell, a record efficiency of 28.14% is obtained with great stability for the efficiency maintaining 96% of its original value for 500 h under one‐sun ...
Chun‐Hsiao Kuan   +12 more
wiley   +1 more source

Improving Cyclohexane Yield from Hydrogenation Benzene with a Modified Multistage Separation Design

open access: yesJournal of Chemical Engineering Research Progress
Cyclohexane is a compound that is widely used in various industrial applications as a chemical intermediate. Apart from that, this compound can also be used to produce solvents, insecticides and plasticizers. With the large use of cyclohexane, production
Nabihan Firas Faiq   +4 more
doaj   +1 more source

Optimization of Cyclohexanol and Cyclohexanone Yield in the Photocatalytic Oxofunctionalization of Cyclohexane over Degussa P-25 under Visible Light

open access: yesMolecules, 2019
The sustainable transformation of basic chemicals into organic compounds of industrial interest using mild oxidation processes has proved to be challenging.
Adolfo Henríquez   +4 more
doaj   +1 more source

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