Results 111 to 120 of about 2,296 (262)

MASS SPECTROMETRY AND CHEMICAL SYNTHESIS. THE CASE OF SOME SUBSTITUTED SPIRO [1,3-BENZODIOXOLE-2, 1′‐CYCLOHEXANES]

, 1986
he electron impact mass spectrometric behaviour of some substituted spiro [1, 3- benzodioxole-2, 1′-cyclohexanes] has been studied in detail with the aid of linked scans and exact mass measurements.
Traldi P., Podda G, Pelli B, MACCIONI, ANNA MARIA, FADDA, ANNA MARIA   +4 more
core  

Phase I Metabolism of Novel Phencyclidine Derivative 3‐Cl‐PCP: In Vitro Studies With Pooled Human Liver Microsomes and Investigation of a Post‐Mortem Case

Drug Testing and Analysis, EarlyView.
A fatal 3‐chloro‐phencyclidine (3‐Cl‐PCP) intoxication was investigated by analyzing postmortem samples and a pooled human liver microsomes assay. Tentative metabolite identification was performed by liquid chromatography‐quadrupole time‐of‐flight mass spectrometry (LC‐QTOF‐MS). Seven phase I metabolites were identified.
Johannes Kutzler, Tobias Veit, Thomas Keller, Volker Auwärter   +3 more
wiley   +1 more source

Air Stability of Sulfide Solid Electrolytes: From Theoretical Insights to Practical Solutions

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This paper reviews research progress on the air stability of SSEs, covering their instability mechanisms and modification strategies, while outlining core challenges and future directions for practical applications. Sulfide solid electrolytes are pivotal for enabling high‐performance all‐solid‐state batteries due to their high ionic conductivity and ...
Hongbing Ding, Yue Hu, Xin Li, Yang Su, Xinlu Wang, Hongbo Zhang, Guixia Liu, Wensheng Yu, Xiangting Dong, Jinxian Wang, Xin Wang   +10 more
wiley   +1 more source

Lithium Diisopropylamide‐Mediated Ring‐Opening of Tetrahydrofuran in the Synthesis of Polyhydroxylated Indolizidines

European Journal of Organic Chemistry, EarlyView.
Chiral tri‐ and pentahydroxy spirocyclopentane‐indolizidines were synthesized using lithium diisopropylamide “LDA” promoted diallylation and tetrahydrofuran “THF” ring‐opening in a one‐pot procedure as a key step. The sequence leading to the targeted hydroxy‐spiroindolizidines was achieved by cis‐dihydroxylation followed by reduction of the enamine and
Paula Fraňová, Peter Šafář, Marchalín Štefan, Petra Pažitná, Ivana Žídeková, Ján Moncol, Adam Daïch   +6 more
wiley   +1 more source

Pt/C‐Catalyzed Deuteration of Polycyclic Aromatic Hydrocarbons with Suppressed Arene Hydrogenation

European Journal of Organic Chemistry, EarlyView.
An additive‐enabled Pt/C protocol promotes hydrogen–deuterium exchange in fused polycyclic aromatic hydrocarbons (PAHs) in D2O/2‐PrOH at 80 °C. Decalin suppresses undesired ring hydrogenation while accelerating on‐ring H–D exchange, furnishing highly deuterated PAHs (PAHs‐dn).
Naoya Sakurada, Sae Tomoto, Naoki Oka, Tomohiro Ichikawa, Takashi Shigeta, Hironao Sajiki, Takashi Ikawa   +6 more
wiley   +1 more source

Structure and dynamics of radical cations of selectively deuteriated cyclohexanes: an ESR and ab initio study

, 1998
An ESR study was carried out to elucidate the static and dynamic Jahn-Teller structures of the radical cations of selectively deuteriated cyclohexanes in a cC(6)F(12) matrix, formed by exposure to ionizing radiation at low temperature.
Shiotani, M, Wang, P,, Lunell, S
core  

Activation of Aryl Halides by Triplet–Triplet Annihilation Upconversion Enabling Coupling Processes Under an Open‐to‐Air Environment

European Journal of Organic Chemistry, EarlyView.
Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez, Paola Domínguez Domínguez, M. Consuelo Jiménez, David Díaz Díaz, Raúl Pérez‐Ruiz   +4 more
wiley   +1 more source

Heteroatom location‐ and orientation mode‐dependent reverse intersystem crossing rate in multiple resonance emitters

FlexMat, EarlyView.
By constructing two pairs of isomers with different heteroatom anchoring positions, the relationship between heteroatom location and orientation mode and reverse intersystem crossing rate constant (kRISC) in multiple resonance (MR) emitters is systematically investigated.
Tingting Huang, Yincai Xu, Yupei Qu, Xinliang Cai, Jinbei Wei, Yue Wang   +5 more
wiley   +1 more source

Recent advances in multifunctional soft robots: A materials–structures–systems co‐design perspective for synergistic integration

FlexMat, EarlyView.
Abstract Soft robots, engineered from highly compliant materials, offer superior adaptability and safety in unstructured environments compared to their rigid counterparts. Recent advancements, fueled by bio‐inspiration and material programmability, have led to the rapid co‐evolution of their core modules: actuation, sensing, protection, energy, and ...
Qiulei Liu, Zicao Peng, Chong Sun, Haitao Yang   +3 more
wiley   +1 more source

Lead‐free halide perovskites for efficient light‐emitting devices

FlexMat, EarlyView.
Overview of Lead‐free metal halide perovskites with different categories and optoelectronic application directions, including solid‐state lighting, light‐emitting diodes, piezoluminescence, flexible electronics, scintillators and CPL emitters. Abstract Lead halide perovskites exhibit promising optoelectronic properties for optoelectronic applications ...
Yueqi Shen, Kefan Meng, Yiqi Zhao, Chaoran Zhou, Jiaye Shu, Di Zhang, Chengqian Cao, Wanxin Chen, Yefeng Zhou, Weihua Ning   +9 more
wiley   +1 more source