Results 11 to 20 of about 1,573 (220)

Stereoselective intermolecular radical cascade reactions of tryptophans or ɤ-alkenyl-α-amino acids with acrylamides via photoredox catalysis

open access: yesNature Communications, 2022
Photocatalytic radical cascade reactions enable the facile construction of diverse cyclic compounds, though they rely on templated precursors. In this paper, the authors report on stereoselective intermolecular radical cascade reaction between tryptophan
Jiang-Tao Li   +5 more
doaj   +1 more source

Living supramolecular polymerization of fluorinated cyclohexanes

open access: yesNature Communications, 2021
Living supramolecular polymerization can produce precise covalent polymers, but the scope of monomers is still narrow. Here the authors show a molecular platform for living supramolecular polymerization that is based on the unique structure of all-cis 1 ...
Oleksandr Shyshov   +8 more
doaj   +1 more source

Oral preanesthetic medication in children ... comparison between midazolam alone and in combination with ketamine: a systematic review and meta-analysis

open access: yesBrazilian Journal of Anesthesiology, 2023
Background: Up to 60% of pediatric surgical patients develop high levels of preoperative anxiety. This study compared the effects of oral combinations of midazolam and ketamine with oral midazolam alone for pediatric preanesthetic medication.
Get..lio Rodrigues de Oliveira Filho   +3 more
doaj   +1 more source

Trisubstituted Cyclohexanes / Trisubstituted Cyclohexanes

open access: yesZeitschrift für Naturforschung B, 1985
C-Tertiarv vinylketones or the corresponding masked vinylketone derivatives react with pyrrolidin-2-one in the system sodium hydride.dimethylsulfoxide to substituted cyclohexanes of the 1,3.5- and sometimes additionally of the 1,2.4-type. Only acetophenone Mannich bases bear­ing a p-hydroxy or a dimethylamino group failed in cyclization.
Hans Mohrle   +3 more
openaire   +1 more source

Complexation and Structure Elucidation of the Axial Conformers of Mono- and (±)-trans-1,2-Disubstituted Cyclohexanes by Enantiopure Alleno-Acetylenic Cage Receptors

open access: yesCHIMIA, 2018
Single crystal X-ray diffraction is a powerful method to unambiguously characterize the structure of molecules with atomic resolution.
Cornelius Gropp, Nils Trapp
doaj   +1 more source

Novel Ring Systems: Spiro[Cycloalkane] Derivatives of Triazolo- and Tetrazolo-Pyridazines

open access: yesMolecules, 2021
In orderto synthesize new pyridazine derivatives anellated with different nitrogen heterocyclic moieties, spiro[cycloalkane]pyridazinones were transformed into the corresponding thioxo derivatives via a reaction with phosphorus pentasulfide. The reaction
Csilla Sepsey Für   +6 more
doaj   +1 more source

Silacyclohexanes, Sila(hetero)cyclohexanes and Related Compounds: Structure and Conformational Analysis

open access: yesMolecules, 2020
Conformational analysis of Si-mono- and Si,Si-disubstituted silacyclohexanes as well as their analogues with a heteroatom(s) in the ring is reviewed with the focus on the recent results.
Bagrat A. Shainyan
doaj   +1 more source

Anti-Austerity Activity of Thai Medicinal Plants: Chemical Constituents and Anti-Pancreatic Cancer Activities of Kaempferia parviflora

open access: yesPlants, 2021
Human pancreatic tumor cells have an intrinsic ability to tolerate nutrition starvation and survive in the hypovascular tumor microenvironment, the phenomenon termed as “austerity”.
Sijia Sun   +9 more
doaj   +1 more source

A BRIEF OVERVIEW OF SPECTROSCOPIC STUDIES OF CYCLOHEXANE AND ITS DERIVATIVES [PDF]

open access: yesVestnik Issyk-Kulʹskogo universiteta
This paper presents the results of comprehensive research on the structure of condensed phases of monosubstituted cyclohexanes and the dynamics of their rearrangement under the influence of thermal motion.
Artikov A.
doaj   +1 more source

Volatile hydrocarbons from endophytic fungi and their efficacy in fuel production and disease control

open access: yesEgyptian Journal of Biological Pest Control, 2018
Endophytic fungi are the microorganisms which asymptomatically colonize internal tissues of plant roots and shoots. Endophytes produce a broad spectrum of odorous compounds with different physicochemical and biological properties that make them useful in
B. Shankar Naik
doaj   +1 more source

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