Results 221 to 230 of about 55,695 (341)

Synthesis of an N‐Galactosyl Norbornane Aziridine and its Potent Mixed Inhibition of Aspergillus oryzae β‐Galactosidase

open access: yesChemBioChem, EarlyView.
An N‐galactosyl aziridine is found to have μM range mixed inhibition constants (Ki and Ki’) for a fungal β‐galactosidase. Aziridine‐bearing cyclic polyols are established as irreversible covalent inhibitors of glycosyl hydrolases and have been employed as activity‐based probes. In the present study, the stereoselective synthesis of a novel N‐galactosyl
Aaron McCormack   +3 more
wiley   +1 more source

Fe─Co Synergism in the Heterogeneous Catalytic Conversion of Cyclohexane to KA Oil

open access: yesChemCatChem, EarlyView.
This research aimed to investigate the potential of heterogeneous Fe‐Co catalysts supported on Alumina in the oxidation of cyclohexane to cyclohexanol and cyclohexanone (KA oil). Different catalysts have been synthesized by sol‐immobilization, wetness impregnation and inverse microemulsion, revealing a different catalytic activity and selectivity ...
Marta Stucchi   +6 more
wiley   +1 more source

Modulation of the Acidity of HY, HBETA, and HZSM‐5 Zeolites by Lanthanum Incorporation for Selective Gasoline Desulfurization in the FCC Riser

open access: yesChemCatChem, EarlyView.
Desulfurization in the FCC riser is achieved by modifying zeolite catalysts with La3+ ions, promoting H2S formation from thiophenic compounds while suppressing secondary reactions. This approach enhances gasoline quality by increasing selectivity for H2S and enabling efficient condensation and alkylation, supporting cleaner fuel production and ...
Ronaldo C. Santos   +8 more
wiley   +1 more source

Aerobic Cyclohexane Oxidation Catalyzed by Vanadium‐Substituted LaCoO3 Perovskites in the Liquid Phase

open access: yesChemCatChem, EarlyView.
LaVxCo1‐xO3 perovskite catalysts achieve highly efficient and selective cyclohexane oxidation to KA oil with molecular oxygen under mild conditions in the liquid phase. Spin trap EPR confirms a free‒radical pathway, while post‒reaction analysis reveals a partially reduced catalyst surface that drives hydroperoxide decomposition, signifying the catalyst'
Akhil Hareendran   +12 more
wiley   +1 more source

Ethylene-Cyclohexane-Telomer System

open access: bronze, 1968
Masamori Yamabe   +3 more
openalex   +2 more sources

Glutathione Threshold‐Triggered Selective Breakability of Organosilica Nanocapsules

open access: yesChemCatChem, EarlyView.
Replacing tetraethoxy orthosilicate (TEOS) by tetramethoxy orthosilicate (TMOS) as silica precursor to synthesize cleavable organosilica nanocapsules enabled the effective and selective entrapment of a positively charged protein as Cytochrome C (CytC) and a much more favorable breakability and kinetics release when exposed to high glutathione (GSH ...
Andrea Mosseri   +5 more
wiley   +1 more source

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