Results 1 to 10 of about 35,479 (263)

Ruthenium-doped Titania-pillared Clay for The Selective Catalytic Oxidation of Cyclohexene: Influence of Ru Loading

open access: goldBulletin of Chemical Reaction Engineering & Catalysis, 2019
A series of ruthenium-based catalysts supported on acid-activated montmorillonite (PILC) and interspersed with titanium (Ru/Ti-PILCs) were prepared with various amounts of ruthenium. Their catalytic performances in the selective oxidation of cyclohexene,
Ahmed Dali   +4 more
doaj   +3 more sources

A Mild Catalytic Oxidation System: FePcOTf/H2O2 Applied for Cyclohexene Dihydroxylation [PDF]

open access: goldMolecules, 2015
Iron (III) phthalocyanine complexes were employed for the first time as a mild and efficient Lewis acid catalyst in the selective oxidation of cyclohexene to cyclohexane-1,2-diol.
Baocheng Zhou, Wenxing Chen
doaj   +2 more sources

Asymmetric Hydride Shift Reactions Catalyzed by Chiral Aluminium Complexes. [PDF]

open access: yesAngew Chem Int Ed Engl
An asymmetric intramolecular hydride shift reaction has been developed that is catalyzed by Al Lewis acids in conjunction with a chiral BINOL‐derived ligand. Racemic THP substrates are transformed into cyclohexene products via an intermediate prochiral enone; which undergoes a key 1,5‐hydride shift reaction.
Amer MM   +4 more
europepmc   +3 more sources

Reactive Distillation for the Production of Cyclohexanol: Experiments and Simulations [PDF]

open access: yesChemical and Biochemical Engineering Quarterly, 2021
Cyclohexanol is an organic chemical intermediate product widely used in chemical industry and commonly produced by cyclohexene hydration. Because of the low mutual solubility of cyclohexene and water, the reaction is limited by chemical equilibrium ...
D. Sun, H. Tian, J. Sun, W. Xu
doaj   +1 more source

Crystal structure of (+)-(1S,5S,6S,7S,10S,11S,16S)-16-hydroxy-7-(methoxymethoxy)-11,15,18,18-tetramethyl-3,13-dioxo-2,4-dioxatetracyclo[12.3.1.01,5.06,11]octadec-14-en-10-yl benzoate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2021
In the fused tetracyclic system of the title compound, C29H36O9, the five-membered dioxolane ring adopts a twist conformation; the two adjacent C atoms deviate alternately from the mean plane of the other three atoms by −0.252 (6) and 0.340 (6) Å.
Takeshi Oishi   +3 more
doaj   +1 more source

Gold Clusters Immobilized by Post-Synthesis Methods on Thiol-Containing SBA-15 Mesoporous Materials for the Aerobic Oxidation of Cyclohexene: Influence of Light and Hydroperoxide

open access: yesChemistry, 2023
Gold nanospecies produced by a historically inspired two-liquid phase system were immobilized on plate-like mesoporous silica, SBA-15, functionalized with mercaptopropyl groups by a post-synthesis method, and the resulting materials were tested in the ...
Rafael Delgado   +5 more
doaj   +1 more source

Investigation of cyclohexene thermal decomposition and cyclohexene + OH reactions

open access: yesCombustion and Flame, 2023
Cyclohexene is a common intermediate in the oxidation of cyclohexane and alkyl-substituted cyclohexanes. It also plays an important role in the formation of polycyclic aromatic hydrocarbons (PAHs) by providing a route for the first aromatic ring. Two types of reactions are highly important in cyclohexene kinetics, i.e., H-abstraction by OH radicals and
Liu, Dapeng, Farooq, Aamir
openaire   +2 more sources

SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA [PDF]

open access: yesمجلة جامعة الانبار للعلوم الصرفة, 2012
This research concerned with the reaction of Aryl- benzoylchloride with 1,3-cyclohexanedione in aqueous media (which has been catalyzed by p-dodecylbenezenesulfonic acid (DBSA) or sodiumdodecylsulfate (SDS)).
MARWAN M. F. AL-HEETY
doaj   +1 more source

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