Results 11 to 20 of about 20,154 (280)

Neolignans and polyoxygenated seco-cyclohexenes from the stems and leaves of Piper suipigua Buch.-Ham. ex D. Don

open access: yesNatural Product Research, 2021
Five new compounds including, a neolignan, eupomatenoid-19 (1) and four polyoxygenated seco-cyclohexenes, artahongkongenes G-J (2–5), together with fifteen known compounds (6–20) were isolated from the stems and leaves of Piper suipigua Buch.-Ham.
Jariya Masranoi   +6 more
semanticscholar   +1 more source

Investigation of cyclohexene thermal decomposition and cyclohexene + OH reactions

open access: yesCombustion and Flame, 2023
Cyclohexene is a common intermediate in the oxidation of cyclohexane and alkyl-substituted cyclohexanes. It also plays an important role in the formation of polycyclic aromatic hydrocarbons (PAHs) by providing a route for the first aromatic ring. Two types of reactions are highly important in cyclohexene kinetics, i.e., H-abstraction by OH radicals and
Liu, Dapeng, Farooq, Aamir
openaire   +2 more sources

One-pot and metal-free synthesis of 3-arylated-4-nitrophenols via polyfunctionalized cyclohexanones from β-nitrostyrenes

open access: yesBeilstein Journal of Organic Chemistry, 2020
β-Nitrostyrenes underwent a Diels–Alder reaction with Danishefsky’s diene to afford cyclohexenes together with the corresponding hydrolyzed products, 3-arylated-5-methoxy-4-nitrocyclohexanones.
Haruyasu Asahara   +2 more
doaj   +1 more source

Chemo- and Regioselective Synthesis of Acyl-Cyclohexenes by a Tandem Acceptorless Dehydrogenation-[1,5]-Hydride Shift Cascade

open access: yesJournal of the American Chemical Society, 2020
An atom-economical methodology to access substituted acyl-cyclohexenes from pentamethylacetophenone and 1,5-diols is described. This process is catalyzed by an iridium(I) catalyst in conjunction with a bulky electron rich phosphine ligand (CataCXium A ...
Lewis B. Smith   +3 more
semanticscholar   +1 more source

Polyoxygenated seco-cyclohexenes derivatives from flower and leaf extracts of Desmos cochinchinensis and their α-glucosidase inhibitory activity

open access: yesHeliyon, 2020
Phytochemical investigations from the flower and leaf extracts of D. cochinchinensis resulted in the isolation and structural elucidation of five new polyoxygenated seco-cyclohexene derivatives, desmoscochinchinenes A-E (1–5), together with 11 known ...
Virayu Suthiphasilp   +6 more
doaj   +1 more source

Secondary Metabolites of Lasiodiplodia theobromae: Distribution, Chemical Diversity, Bioactivity, and Implications of Their Occurrence

open access: yesToxins, 2020
Lasiodiplodia theobromae is a plant pathogenic fungus from the family Botryosphaeriaceae that is commonly found in tropical and subtropical regions.
Maria Michela Salvatore   +2 more
doaj   +1 more source

New entry to the enantioselective formation of substituted cyclohexenes bearing an all-carbon quaternary stereogenic center.

open access: yesChirality, 2020
Enantioselective formation of cyclohexene derivatives bearing an all-carbon quaternary stereogenic center is described. The racemic cyclohexenes are readily transformed to chiral substituted cyclohexenes in good yield with excellent enantioselectivity ...
Keita Komine   +5 more
semanticscholar   +1 more source

Stereospecific Ring Contraction of Bromocycloheptenes through Dyotropic Rearrangements via Nonclassical Carbocation-Anion Pairs [PDF]

open access: yes, 2018
Experimental and theoretical evidence is reported for a rare type I dyotropic rearrangement involving a [1,2]-alkene shift, leading to the regio- and stereospecific ring contraction of bromocycloheptenes.
Champagne, Pier Alexandre   +6 more
core   +1 more source

Oxidation of acyclic alkenes and allyl and benzyl ethers with DIB/t-BuOOH/Mg(OAc)2 [PDF]

open access: yes, 2012
Oxidation of (11Z)-1′,2′-didehydrostemofoline with DIB/TBHP/Mg(OAc)2·4H2O resulted in oxidative cleavage of the C-11-C-12 double bond instead of the desired allylic oxidation of the 1-butenyl side chain. Stemofoline gave a similar result.
Pyne, SG, Sastraruji, T, Ung, AT
core   +1 more source

Green process for adipic acid synthesis: oxidation by hydrogen peroxide in water micromelusions using Benzalkonium Chloride C12-14 surfactant [PDF]

open access: yes, 2012
Adipic acid was synthesized by the oxidation of cyclohexene using 30% hydrogen peroxide in a microemulsion in the presence of sodium tungstate as catalyst.
Cognet, Patrick   +3 more
core   +3 more sources

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