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The reaction of tetramesityldisilene with cyclohexene oxide and cyclohexene sulfide
Journal of the Chemical Society, Chemical Communications, 1993Reaction of tetramesityldisilene, 1, with Cyclohexene oxide in benzene at 80 °C gives silyl enol ether, 2, as the major product along with the products of epoxide deoxygenation, Cyclohexene and the known tetramesityldisilaoxirane,3; reaction of 1 with Cyclohexene sulfide occurs rapidly at room temp, to give the known tetramesityldisilathiirane, 6, and ...
John E. Mangette +2 more
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Isolation of cyclohexene oxide from the chromyl chloride oxidation of cyclohexene
Journal of the Chemical Society, Chemical Communications, 1973Oxidation of cyclohexene with chromyl chloride gives, among other products, cyclohexene oxide in low yield.
Frank W. Bachelor, Ukken O. Cheriyan
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Substituent effects in cyclohexenes
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1980The effects of the C1-CH3 group in the13C spectra of trans-4,5-dimethylcyclohex-4-ene-1,2-dicarboxylic and syn-txans-Δ4-octalin-1,2-dicarboxylic acid and their diesters show the existence in solution of a considerable proportion of the trans-a,a forms of these compounds.
V. A. Denisenko +3 more
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Uncatalysed oxidation of cyclohexene
Chemical Engineering Science, 1999Abstract The oxidation products of cyclohexene find several applications as intermediates for the manufacture of useful chemicals like cyclohexanol, cyclohexenol/cyclohexenone, cyclohexadiene, etc. The uncatalysed oxidation of cyclohexene with molecular oxygen was studied in a batch reactor.
S.M. Mahajani, M.M. Sharma, T. Sridhar
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Phosphonomethylation of cyclohexene oxides
The Journal of Organic Chemistry, 1993The tradeoff between synthetic directness and regioselectivity during oxirane ring opening is examined for two strategies used to phosphonomethylate cyclohexene oxide and substituted cyclohexene oxides derived from quinic acid and myo-inositol. Direct phosphonomethylation of the cyclohexene oxides utilizes diisopropyl lithiomethanephosphonate ((C 3 H 7
Jean Luc Montchamp +2 more
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Biocenversion of cyclohexene derivatives
Applied Microbiology and Biotechnology, 1984Bioconversion of new methylcyclohexene derivatives with bulky side chains ending in aromatic or heteroaromatic rings by Streptomyces natalensis and Mycobacterium smegmatis results in monohydroxylation of the cyclohexene ring. Further oxidation of the hydroxyl group into a keto group is effected only with M. smegmatis.
I. Belič +3 more
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Ultrafast Dynamics of Cyclohexene and Cyclohexene-d10 Excited at 200 nm
Journal of the American Chemical Society, 2001By exciting cyclohexene in the gas phase at 200 nm and probing it by nonresonant multiphoton ionization with mass-selective detection of the ion yields, we found four time constants tau(i) (20, 47, 43, 350 fs). Whereas deuteration lengthens tau2 by a factor of 1.4, the other constants do not change.
W, Fuss, W E, Schmid, S A, Trushin
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THE RADIOLYSIS OF CYCLOHEXANE: II. CYCLOHEXANE–CYCLOHEXENE SOLUTIONS AND PURE CYCLOHEXENE
Canadian Journal of Chemistry, 1960The γ-radiolysis of cyclohexane–cyclohexene solutions and of pure cyclohexene has been investigated. The previously determined yields of the two activated species in irradiated cyclohexane have been confirmed. G(c-C6H12′′) = 3.0 ± 0.3 and G(c-C6H12′) = 2.4 ± 0.3.The yields of the main products of cyclohexene radiolysis are G(H2) = 1.2, G(c-C6H12) = 1 ...
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THE AMMONOMERCURATION OF CYCLOHEXENE
Canadian Journal of Chemistry, 1965not available
D. Chow, J. H. Robson, George F Wright
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2001
(1; R = 1-pyrrolidino) [1125-99-1] C10H17N (MW 151.28) InChI = 1S/C10H17N/c1-2-6-10(7-3-1)11-8-4-5-9-11/h6H,1-5,7-9H2 InChIKey = KTZNVZJECQAMBV-UHFFFAOYSA-N (2; R = 4-morpholino) [670-80-4] C10H17NO (MW 167.28) InChI = 1S/C10H17NO/c1-2-4-10(5-3-1)11-6-8-12-9-7-11/h4H,1-3,5-9H2 InChIKey = IIQFBBQJYPGOHJ-UHFFFAOYSA-N (3; R = 1 ...
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(1; R = 1-pyrrolidino) [1125-99-1] C10H17N (MW 151.28) InChI = 1S/C10H17N/c1-2-6-10(7-3-1)11-8-4-5-9-11/h6H,1-5,7-9H2 InChIKey = KTZNVZJECQAMBV-UHFFFAOYSA-N (2; R = 4-morpholino) [670-80-4] C10H17NO (MW 167.28) InChI = 1S/C10H17NO/c1-2-4-10(5-3-1)11-6-8-12-9-7-11/h4H,1-3,5-9H2 InChIKey = IIQFBBQJYPGOHJ-UHFFFAOYSA-N (3; R = 1 ...
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