Future Postharvest and Food, EarlyView.1) The samples from Liupanshui orchards in Guizhou province exhibited relatively higher levels of sweetness and sourness. 2) The most comprehensive aroma profile to date for ‘Hongyang’ kiwifruit was established. 3) Among the 15 differential volatile organic compounds (VOCs), (E)‐3‐octen‐2‐one and 2‐pentanoylfuran were key markers distinguishing ...
Jinfeng Liu +8 more
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CLXXXVII.—Experiments on the synthesis of the terpenes. Part I (continued). Resolution of dl-1-methyl-Δ1-cyclohexene-4-carboxylic acid and synthesis of the optically active modifications of terpineol [PDF]
, 1908 Kenneth C. Fisher, W. H. Perkin
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Mass spectrometry in structural and stereochemical problems. Part 178 - The electron-impact promoted fragmentation of 1,2-cyclohexene oxide [PDF]
Mass spectra of 1,2-cyclohexane oxide and three deuterium labeled ...
Brown, P., Djerassi, C., Strong, M. K.
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Nano Select, EarlyView.This article reviews the recent advances in the strategies of preparation, characterizations, catalytic efficiency, and plausible mechanisms of metalloporphyrin‐based magnetic nanocatalysts focused on the oxidation of olefins during 2013–2024. ABSTRACT Catalytic oxidation of olefins is a vital class of reaction that has drawn huge interest in both ...
Sara Payamifar +5 more
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CXXXVII.—The cis- and trans-modifications of 1-methyl-cyclohexan-2-ol-4-carboxylic acid and their conversion into 1-methyl-Δ1-cyclohexene-4-carboxylic acid [PDF]
, 1908 Andrew Meldrum, W. H. Perkin
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Organophotocatalytic Reduction of Benzenes to Cyclohexenes
Journal of the American Chemical SocietyThe reduction of abundant benzene rings to scarce C(sp3)-rich motifs is invaluable for drug design as C(sp3) content is known to correlate with clinical success. Cyclohexenes are attractive targets as they can be rapidly elaborated into large product libraries and are stable against rearomatization.
Kirti Devi +2 more
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Exploring Unspecific Peroxygenase Selectivity with Diverse Hydrocarbon Substrates
ChemistryOpen, EarlyView.Unspecific peroxygenases (UPOs) are versatile enzymes that can be used for different reactions. However, selectivity of UPOs needs to be evaluated for the desired application. Thus, the selectivity of a panel of UPOs was evaluated in this work, and it revealed diverse reactivity profiles depending on the enzyme and substrate.
Essi Rytkönen +3 more
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ChemistryOpen, EarlyView.The enamine formation catalyzed by a flexible asymmetric tripeptide is studied computationally. The catalyst's ability to reorganize plays a crucial role, enabling the reaction and providing multiple pathways for its occurrence. Furthermore, issues related to conformational search, method selection, and model system choices are discussed.
Irina Osadchuk, Tõnis Kanger
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Development of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels–Alder Reaction
Angewandte Chemie, Volume 137, Issue 33, August 11, 2025.A strain‐promoted Diels–Alder reaction of the vinylated cyclic allene, a highly reactive strained all‐carbon diene, was developed. Activation of the Kobayashi‐type precursor with fluoride ion generated the vinyl cyclic allene, which was trapped by dienophiles to produce decalin derivatives under mild conditions.
Haruki Mizoguchi +4 more
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Redox Reorganization: Aluminium Promoted 1,5-Hydride Shifts Allow the Controlled Synthesis of Multisubstituted Cyclohexenes. [PDF]
Angew Chem Int Ed Engl, 2023 Smith LB +8 more
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