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Chemistry - A European Journal, 2023
Although challenging, the distant C-H functionalization with precision is quite rewarding and has long been intriguing. Tailoring an appropriate template accomplishes the job but the prerequisite sets the limitation.
Attunuri Nagireddy, Maddi Sridhar Reddy
exaly +2 more sources
Although challenging, the distant C-H functionalization with precision is quite rewarding and has long been intriguing. Tailoring an appropriate template accomplishes the job but the prerequisite sets the limitation.
Attunuri Nagireddy, Maddi Sridhar Reddy
exaly +2 more sources
Studies on the cyclometallation of ferrocenylimines
Journal of Organometallic Chemistry, 2001Abstract This review describes the cyclometallation reaction, including cyclomercuration, cyclopalladation and cycloplatination of Schiff base type of ferrocenylimines as well as the transmetallation reaction of cyclometallated ferrocenylimines and the stereochemistry associated with these reactions.
Chenxia Du, Xiuling Cui, Shouquan Huo
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Cyclometallation of Alkylphosphines
, 1998 Catalytic activation of alkane C-H bonds is of great technological importance in the efficient utilization of petrochemical feedstocks.1 Phosphines are widely used in many catalysts as co-ligands to control a wide variety of operational variables such as solubility in different solvents, stereospecificity, and regiospecificity.2 A very large number of ...
Michael T. Benson, Thomas R. Cundari
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Metal controlled regioselectivity in the cyclometallation of 2-(1-naphthyl)-pyridine.
Chemical Communications, 2015 Cyclometallation of 2-(1-naphthyl)-pyridine is described. While cyclopalladation results in a five-membered metallacycle, cycloauration displays a completely orthogonal regioselectivity, resulting in the six-membered ring analogue.
M. Kondrashov, S. Raman, O. Wendt
semanticscholar +3 more sources
A direct access to heterobimetallic complexes by roll-over cyclometallation.
Chemical Communications, 2017 Creation of a novel chelating site by roll-over cyclometallation opens up a new strategy for a rapid access to heterobimetallic complexes. Combinations of iridium(iii) with palladium(ii) or platinum(ii) have exemplarily been synthesized.
F. Schön +8 more
semanticscholar +2 more sources
Cyclometallation of ferrocenylimines
Journal of Organometallic Chemistry, 1994Yang Jie Wu
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Cyclometallation of Heterocycles: A Reliable Strategy for Selective Functionalization
Comments on Inorganic Chemistry, 2012 Heterocyclic compounds are of paramount importance in essentially all fields of chemistry and in our daily life. Therefore, the synthesis and modification of such compounds is a constantly expanding field in synthetic chemistry.
Esteban P Urriolabeitia, Luciano Cuesta
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