Results 41 to 50 of about 14,858 (206)

Koordinationschemie perhalogenierter Cyclopentadiene und Alkine, X [PDF]

open access: yes, 1992
Coordination Chemistry of Perhalogenated Cyclopentadienes and Alkynes, X[1]. - Synthesis and Molecular Structure of a Cyclopentadienyl-1,3-dithiol Complex, [C5Cl3(SH)2]Mn(CO)3 The reaction of [C5Cl4Li]Mn(CO)3 with elemental sulfur leads to [C5Cl4SLi]Mn(
Akabori   +15 more
core   +1 more source

Notiz zur Synthese von Fulvenen nach Freiesleben

open access: yesCHIMIA, 1974
Attempts to reproduce the synthesis of fulvenes claimed by Freiesleben (condensation of cyclopentadiene and carbonyl compounds in the presence of primary and secundary amines) are not successful, as far as the yields are concerned.
M. Neuenschwander, B. Granwehr
doaj   +1 more source

A multi-substrate screening approach for the identification of a broadly applicable Diels–Alder catalyst

open access: yesNature Communications, 2019
Investigation of a reaction scope usually starts with the optimization for a model substrate. Here, the authors apply a time-efficient multi-substrate screening approach to identify a general organocatalyst for the Diels–Alder reaction of cyclopentadiene
Hyejin Kim   +8 more
doaj   +1 more source

Controlling thermal reactivity with different colors of light [PDF]

open access: yes, 2017
The ability to switch between thermally and photochemically activated reaction channels with an external stimulus constitutes a key frontier within the realm of chemical reaction control.
Barner-Kowollik, Christopher   +2 more
core   +4 more sources

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

open access: yesAngewandte Chemie International Edition, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh   +5 more
wiley   +1 more source

Di-, Hexa- and Deca-Substituted Decaphenylferrocenes [PDF]

open access: yes, 2005
5-Bromo-1,2,3,4-tetraphenyl-5-p-tolyl-1,3-cyclopentadiene (1a), 5-Bromo-1,4-di-phenyl-2,3,5- tri-p-tolyl-1,3-cyclopentadiene (1b), 5-Bromo-1,2,3,4,5-penta-p-tolyl-1,3-cyclopentadiene (1c), 5- Bromo-1,2,3,4-tetraphenyl-5-p-bromophenyl-1,3-cyclopentadiene (
Schumann, Herbert, Sühring, Klaudia
core   +1 more source

Synthese und Luftvernetzung von Dimethylfulven-Copolymerisaten

open access: yesCHIMIA, 1986
Cationic copolymerization of 6,6-dimethylfulvene (1) with styrene, ethoxyethene, and cyclopentadiene has been investigated. For the system 1 (M1)/cyclopenta-diene (M2) copolymerization-parameters r1 = 21.5 and r2 = 0.053 have been determined; this shows
Ulrich Schädeli, Markus Neuenschwander
doaj   +1 more source

Combining 3D printing and liquid handling to produce user-friendly reactionware for chemical synthesis and purification [PDF]

open access: yes, 2013
We use two 3D-printing platforms as solid- and liquid-handling fabricators, producing sealed reactionware for chemical synthesis with the reagents, catalysts and purification apparatus integrated into monolithic devices.
Cronin, Leroy   +3 more
core   +1 more source

Light‐Induced Reactions of Small‐Membered Cyclic Carbonyl Compounds

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review highlights recent advances in the synthesis and photochemical reactivity of cyclopropenone and cyclobutenedione. These compounds undergo photolysis upon direct excitation, and in some cases, through indirect excitation by photocatalysts. The resulting photogenerated species exhibit unique reactivity profiles that are strongly influenced by ...
Kenji Mishiro
wiley   +1 more source

Synthesis of Pentacycloundecane (PCUD) Based Spiro-Pyrano-Cage Framework via Ring-Closing Metathesis

open access: yesMolbank, 2023
Here, we demonstrate a short synthetic route to pyrano cage systems containing pentacycloundecane units by employing ring-closing metathesis (RCM) as a key step.
Sambasivarao Kotha   +2 more
doaj   +1 more source

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