Results 1 to 10 of about 5,368,405 (121)
Self-assembly using a retro Diels-Alder reaction
Nature Communications, 2021 Despite their great utility in synthetic and materials chemistry, Diels-Alder and retro Diels-Alder reactions have been vastly unexplored in promoting self-assembly processes.
Jaeyoung Park +4 more
doaj +2 more sources
Molecules, 2020 The study of Diels−Alder reactions in materials science is of increasing interest. The main reason for that is the potential thermoreversibility of the reaction.
Jamerson Carneiro de Oliveira +2 more
doaj +2 more sources
eXPRESS Polymer Letters, 2016 The Diels-Alder reaction between N-phenylmaleimide and benzoxazine bearing furan group was investigated for the purpose of successful appliance of self-healing in benzoxazine polymer networks.
Z. Stirn, A. Rucigaj, M. Krajnc
doaj +2 more sources
Trends in the Diels-Alder reaction in polymer chemistry.
Chemical Society Reviews, 2021 The Diels-Alder (DA) reaction is regarded as quite a useful strategy in organic and macromolecular syntheses. The reversibility of this reaction and the advent of self-repair technology, as well as other applications in controlled macromolecular ...
Benoit Briou, B. Ameduri, B. Boutevin
semanticscholar +1 more source
Organics, 2022 The [2+2+2] cycloaddition (homo-Diels–Alder reaction) of N-substituted 1,2,4-triazoline-3,5-diones (TADs) with bicycloalkadienes produces strained heterocyclic compounds.
Gary W. Breton, Kenneth L. Martin
doaj +1 more source
The hexadehydro-Diels-Alder reaction: Benzyne generation via cycloisomerization of tethered triynes
Chemical Reviews, 2021 The hexadehydro-Diels-Alder (HDDA) reaction is the thermal cyclization of an alkyne and a 1,3-diyne to generate a benzyne intermediate. This is then rapidly trapped, in situ, by a variety of species to yield highly functionalized benzenoid products.
Lucas L. Fluegel, T. Hoye
semanticscholar +1 more source
Electric field–catalyzed single-molecule Diels-Alder reaction dynamics
Science Advances, 2021 An electric field promotes an unprecedented stepwise Diels-Alder cycloaddition reaction mechanism. Precise time trajectories and detailed reaction pathways of the Diels-Alder reaction were directly observed using accurate single-molecule detection on an ...
Chen Yang +12 more
semanticscholar +1 more source
Enzymatic intermolecular Diels-Alder reactions in synthesis: From nature to design
Tetrahedron Chem, 2022 The Diels-Alder (D-A) reaction is one of the most critical chemical transformations to construct C–C bonds with predictable regio- and stereo-selectivities. It has been widely used as a retrosynthetic disconnection in synthetic chemistry.
Lei Gao, Jun Yang, Xiaoguang Lei
doaj +1 more source
Reversible Diels–Alder Reactions with a Fluorescent Dye on the Surface of Magnetite Nanoparticles
Molecules, 2021 Diels–Alder reactions on the surface of nanoparticles allow a thermoreversible functionalization of the nanosized building blocks. We report the synthesis of well-defined magnetite nanoparticles by thermal decomposition reaction and their ...
Siyang He, Guido Kickelbick
doaj +1 more source
Green Synthesis and Catalysis, 2020 Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields.
Xixi Song +5 more
doaj +1 more source