Results 31 to 40 of about 7,607,880 (287)

Enzymatic Intermolecular Hetero-Diels–Alder Reaction in the Biosynthesis of Tropolonic Sesquiterpenes

open access: yesJournal of the American Chemical Society, 2019
Diels–Alder reactions are among the most powerful synthetic transformations to construct complex natural products. Despite that increasing of enzymatic intramolecular Diels–Alder reactions have been discovered, natural intermolecular Diels–Alderases are ...
Qi-Bin Chen   +11 more
semanticscholar   +1 more source

Applications of Danishefsky's dienes in asymmetric Oxo-Diels-Alder reactions

open access: yes, 2022
Applications of Danishefsky's dienes in catalytic asymmetric hetero-Diels-Alder (AHDA) reactions or specifically, their asymmetric Oxo-Diels-Alder (AOxo-DA) reactions with appropriate dienophiles are highlighted in detail, including the preparation of
AfsanehTaheri kal Koshvandi (11996987)   +1 more
core   +1 more source

Enzyme-catalyzed inverse-electron demand Diels-Alder reaction in the biosynthesis of antifungal ilicicolin H

open access: yesJournal of the American Chemical Society, 2019
The pericyclases are a growing superfamily of enzymes that catalyze pericyclic reactions. We report a pericyclase IccD catalyzing an inverse-electron demand Diels–Alder (IEDDA) reaction with a rate acceleration of 3 × 105 fold in the biosynthesis of ...
Zhuan Zhang   +6 more
semanticscholar   +1 more source

Data on production and characterization of melamine-furan-formaldehyde particles and reversible reactions thereof

open access: yesData in Brief, 2019
The data present in this article affords insides in the characterization of a newly described bi-functional furan-melamine monomer, which is used for the production of monodisperse, furan-functionalized melamine-formaldehyde particles, as described in ...
Katharina Urdl   +6 more
doaj   +1 more source

Aza-Diels-Alder reaction of both electron-deficient azoalkenes with electron-deficient 3-phencaylideneoxindoles and 3-aryliminooxindol-2-ones

open access: yesGreen Synthesis and Catalysis, 2021
An uncommon aza-Diels-Alder reaction of electron-deficient azoalkenes and electron-deficient 3-phenacylideneoxindoles was successfully developed for convenient construction of the heterocyclic spirooxindoles.
Wenjing Shi, Jing Sun, Chao-Guo Yan
doaj   +1 more source

Diels–Alder Cycloaddition Reactions in Sustainable Media

open access: yesMolecules, 2022
Diels–Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity.
Maria I. L. Soares   +2 more
doaj   +1 more source

Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles [PDF]

open access: yes, 2002
4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans.
Marsden, S.P., Ducept, P.C.
core   +5 more sources

Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

open access: yesNature Communications, 2018
A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox ...
Guoting Zhang   +5 more
doaj   +1 more source

Computational design of an enzyme catalyst for a stereoselective bimolecular Diels-Alder reaction

open access: yesScience, 2010
Biocatalytic Boost Enzymes tend to direct reactions toward specific products much more selectively than synthetic catalysts. Unfortunately, this selectivity has evolved for cellular purposes and may not promote the sorts of reactions chemists are seeking
J. Siegel   +12 more
semanticscholar   +1 more source

Alkenylboronate Tethered Intramolecular Diels−Alder Reactions

open access: yes, 2016
Alkenylboronate Tethered Intramolecular Diels−Alder ...
Robert A. Batey (1417081)   +2 more
core   +4 more sources

Home - About - Disclaimer - Privacy