Results 61 to 70 of about 14,858 (206)
The PyBox–La(OTf)3-catalyzed enantioselective Diels–Alder cycloaddition of 2-alk-2-enoylpyridines with cyclopentadiene is realized, producing enantiopure disubstituted norbornenes, which possess four contiguous stereocenters and are biologically relevant
Hao Wei +6 more
doaj +1 more source
Synthesis of Simplified Azasordarin Analogs as Potential Antifungal Agents [PDF]
A new series of simplified azasordarin analogs was synthesized using as key steps a Diels–Alder reaction to generate a highly substituted bicyclo[2.2.1]heptane core, followed by a subsequent nitrile alkylation.
Dockendorff, Chris, Wu, Yibiao
core +4 more sources
2,2′-Bis(ferrocenylmethyl)-5,5′-(m-phenylene)di-2H-tetrazole
In the title compound, [Fe2(C5H5)2(C20H16N8)], one of the unsubstituted cyclopentadiene (Cp) rings is disordered over two positions, with site-occupancy factors of 0.609 (19) and 0.391 (19).
Fang Chen
doaj +1 more source
Herein, the topochemical transformation of cobalt‐based layered hydroxides into nanocomposites is investigated using advanced real‐time characterization techniques combined with thermogravimetric analysis. The study reveals how interlayer carboxylic acids direct the transformation pathway, highlighting the role of carbon content and anion length. These
Camilo Jaramillo‐Hernández +5 more
wiley +1 more source
Mechanochemical Regulation of a Photochemical Reaction [PDF]
We introduce the concept of mechanochemically gated photoswitching. Mechanical regulation of a photochemical reaction is exemplified using a newly designed mechanophore based on a cyclopentadiene–maleimide Diels–Alder adduct.
Barber, Ross W. +3 more
core +4 more sources
Mechanochromic Organic Materials: Molecular Mechanisms and Multidimensional Applications
Mechanochromic (MC) organic materials change color in response to mechanical force. This review elucidates the molecular mechanisms (e.g., aggregation‐induced emission, AIE) and explores their multidimensional applications in sensors, anti‐counterfeiting, biomedical devices, and structural health monitoring, providing a roadmap for future smart ...
Xiaozhe Yin +5 more
wiley +1 more source
2-(4-Ferrocenylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
In the title compound,, [Fe(C5H5)(C17H20BO2)], the two near parallel cyclopentadienyl rings of the ferrocene group are eclipsed. The benzene ring is tilted with respect to the attached cyclopentadiene ring by 17.0 (1)° and by 24.2 (1 ...
J. D. Paauwe, Peter D. W. Boyd
doaj +1 more source
Asymmetric Diels-Alder Reaction of 5,5,5-Trichloro-3-penten-2-one and Its Related Compound [PDF]
Diels-Alder reactions of 5,5,5-trichloro-3-penten-2-one and ethyl 4,4,4-trichloro-2-butenoate with cyclopentadiene in the presence of a chiral Lewis acid gave exo-2-acetyl-endo-3-trichloromethyl-bicyclo[2.2.1]hept-5-ene and exo-2-ethoxycarbonyl-endo-3 ...
Nakatsu, Shogo, Tsuboi, Sadao
core +1 more source
Cyclopropenes in Photochemical Reactions
The photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
David Suárez‐García +2 more
wiley +1 more source
The photooxidations of the toxic products sulfide, 2-mercaptoethanol and phenols under partial mineralisation in aqueous alkaline solution and the photooxidation of cyclopentadiene in ethanol in order to produce fine chemicals is described.
Robert Gerdes +4 more
doaj +1 more source

