Results 71 to 80 of about 14,858 (206)
The synthesis, characterization and thermal chemistry of modified norbornenyl PMR endcaps [PDF]
As part of a program to further the understanding of the polymerization of Nadic-Endcapped PMR systems, a series of model Norbornenyl-Imides has been synthesized and their thermal behavior explored.
Malhotra, V. +3 more
core +1 more source
Konjugierte Anorganisch‐Organische Hybrid‐Polymere mit p‐Block Elementen
Der Einfluss unterschiedlicher p‐Block‐Element‐Motive auf die photophysikalischen Eigenschaften konjugierter anorganisch‐organischer Hybridpolymere im Hinblick auf die Anwendung in organischen Elektronikbauteilen wird dargelegt. Die jüngsten Fortschritte beim Einsatz der schwereren Elemente und schwererer Mehrfachbindungen sowie zu diversen (Post ...
Anna‐Lena Thömmes +1 more
wiley +1 more source
[2+2]-cycloadditions of alkenes with the triphenylallenyl cation [PDF]
The triphenylallenyl cation (8), generated from triphenylpropynol (7) and FSO3H, reacts with alkenes to give the allyl cations 12, which may be deprotonated to yield the methyleneccylobutenes 14.
Deno +13 more
core +1 more source
Conjugated Inorganic–Organic Hybrid Polymers with p‐Block Elements
The influence of various p‐block element motifs on the photophysical properties of conjugated inorganic‐organic hybrid polymers is surveyed regarding applications in organic electronics. Recent advances in the use of heavier elements as well as heavier multiple bonds and the development of diverse (post‐)functionalization strategies suggest ample scope
Anna‐Lena Thömmes +1 more
wiley +1 more source
For a better modeling of the importance of the different channels leading to the first aromatic ring, we have compared the structures of laminar rich premixed methane flames doped with several unsaturated hydrocarbons: allene and propyne, because they ...
Benson +31 more
core +2 more sources
Tracking Propagating Perturbations in Chemical Reactions
Tracking the propagation of periodic concentration perturbations within chemical reactions is presented as a powerful strategy for probing reaction connectivity and the kinetics of individual reaction steps. This approach is demonstrated here for the organocatalytic Michael‐type addition of cyclopentadiene to α,β‐unsaturated aldehydes, based on ...
Charlotte Lefebvre, Quentin Duez
wiley +1 more source
1,4-Diferrocenyl-2-methylpiperazine-1,4-diium bis(trifluoroacetate)
In the title compound, [Fe2(C5H5)2(C17H24N2)](CF3COO)2, the cation possesses a crystallographically imposed inversion centre. The methyl group is disordered over two positions of equal occupancy. The Fe—C bond lengths to the two cyclopentadiene
Fang Chen
doaj +1 more source
The oxidation degradation of aromatic compounds [PDF]
A series of experiments were conducted which focused on understanding the role that the O atom addition to aromatic rings plays in the oxidation of benzene and toluene.
Brezinsky, Kenneth, Glassman, Irvin
core +1 more source
The alpha-effect in cyclic secondary amines: new scaffolds for iminium ion accelerated transformations [PDF]
Five-membered secondary amine heterocycles containing an α-heteroatom were prepared and shown to be ineffective as catalysts for the iminium ion catalysed Diels–Alder reaction between cinnamaldehyde and cyclopentadiene.
Cavill, Julie L. +7 more
core +1 more source
In this work, we constructed homomeric high‐density FLPs. By establishing a descriptor model and a novel strategy for dynamic time alignment analysis, we accelerated transition state search by 220‐fold, pioneering a “dynamic dimension” for catalytic performance.
Lingjing Yu +4 more
wiley +1 more source

