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Effects of elemental ratios in CZTSe film on CZTSe/CdS band alignment and inhomogeneity in absorber thermal conductivity

2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC), 2016
CZTSe solar cells with different elemental ratios are compared for their photo-response with low and high illumination densities. Elemental ratios are found not only affecting the defect density, but also Mo/CZTSe/CdS band alignment. Higher Sn/Cu and lower Zn ratio was found more immune to EQE droop at high power illumination, although it yields lower ...
Qiong Chen, Yong Zhang
openaire   +1 more source

Fabrication and Electronic Properties of CZTSe Single Crystals

IEEE Journal of Photovoltaics, 2015
CZTSe single crystals of different compositions were fabricated by solid-state reaction of elements in a sealed ampoule below the melt temperature. About 2-5-mm crystals were achieved without a flux agent, which, when present, can potentially affect defect properties in the material.
Douglas M. Bishop   +4 more
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CZTSe devices fabricated from CZTSSe nanoparticles

2013 IEEE 39th Photovoltaic Specialists Conference (PVSC), 2013
To understand and control the growth paths of kesterite based CZTSe films as prepared from kesterite nanoparticles we investigate films prepared from different chalcogenide ratios in the initial nanoparticles. To do so we introduce a new method for producing kesterite nanocrystals with controlled ratios of sulfur and selenium.
Bryce C. Walker   +4 more
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Overcoming the Voc limitation of CZTSe solar cells

2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC), 2016
The V oc deficit issue is considered to be the most significant limitation of high-performance kesterite devices [1]. Secondary phases, defects, band tailing and interface recombination at the kesterite/CdS heterojunction are possible reasons for the low V oc .
Risch, L.   +10 more
openaire   +2 more sources

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