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Suppressing Element Inhomogeneity Enables 14.9% Efficiency CZTSSe Solar Cells

Advanced Materials
AbstractKesterites, Cu2ZnSn(SxSe1−x)4 (CZTSSe), solar cells suffer from severe open‐circuit voltage (VOC) loss due to the numerous secondary phases and defects. The prevailing notion attributes this issue to Sn‐loss during the selenization. However, this work unveils that, instead of Sn‐loss, elemental inhomogeneity caused by Cu‐directional diffusion ...
Yimeng Li   +8 more
openaire   +2 more sources

Fabrication of 7.2% Efficient CZTSSe Solar Cells Using CZTS Nanocrystals

Journal of the American Chemical Society, 2010
Earth abundant copper-zinc-tin-chalcogenide (CZTSSe) is an important class of material for the development of low cost and sustainable thin film solar cells. The fabrication of CZTSSe solar cells by selenization of CZTS nanocrystals is presented. By tuning the composition of the CZTS nanocrystals and developing a robust film coating method, a total ...
Qijie, Guo   +6 more
openaire   +2 more sources

Development of photovoltaic ceramic tile based on CZTSSe absorber

Materials Letters, 2015
Abstract Ceramic photovoltaic tile based on Cu2ZnSn(S,Se)4 semiconductor has been made by low-cost and easy processing method of preparation. Ceramic tile as alternative of soda-lime glass substrate has been used. The molybdenum thin film was integrated into the ceramic enamel as a back contact.
I. Calvet   +5 more
openaire   +1 more source

Controlled Li Alloying of CZTSSe Absorbers by Electrochemical Treatment

2023
Oral presentation at 2023 MRS Spring ...
Moser, Simon   +4 more
openaire   +1 more source

Enhancing CZTSSe solar cells through electric field induced ion migration

Journal of Materials Chemistry A, 2022
Solar cells made from Cu2ZnSn(S,Se)4 (CZTS)-derived materials have been widely studied for their favourable material properties utilized in photovoltaic energy conversion.
A. O'Neill   +6 more
openaire   +1 more source

Modeling of CZTSSe solar photovoltaic cell for window layer optimization

Optik, 2020
Abstract Large and long-term future development of solar cells requires abundant non-toxic material like silicon. CZTSSe has emerged as next-generation solar material with an excellent candidate having better performance than previously studied compounds.
null Sadanand, DK Dwivedi
openaire   +1 more source

The effect of Rb doping on CZTSSe solar cells

Solar Energy, 2019
Abstract Alkali metal doping is a promising method to enhance the performance of Cu2ZnSn(Se,S)4 (CZTSSe) solar cells due to its excellent effect on Cu(In,Ga)Se2 (CIGS) solar cells. In this work, rubidium (Rb) was doped in CZTSSe absorbers by sputtering Rb doped Cu2ZnSnS4 (CZTS) target with subsequent H2Se contained annealing.
Yixuan Wu   +12 more
openaire   +1 more source

Synthesis and characterization of CZTSSe nanoparticle inks for photovoltaic devices

physica status solidi c, 2015
AbstractCu2ZnSnSe4 (CZTSe) is one of the promising materials as absorber layers in thin film solar cells. It contains earth abundant and non‐toxic elements. With a broad optical band gap at 1.5 eV as well as a high absorbance coefficient of 10–4 cm–1, CZTS is also a good light harvesting material.
Ridvan Ergun, Cagdas Calli, Elif Arici
openaire   +1 more source

Trap density simulations on CZTSSe solar cells with AMPS-1D

Journal of Materials Science: Materials in Electronics, 2018
This work involves the simulation of Cu2ZnSn(S,Se) (CZTSSe) solar cell in analysis of microelectronic and photonic structures (AMPS-1D) while taking into account previous experimental and theoretical data on CZTS, CZTSe, CZTSSe, CdS and ZnO based devices. We start from the results of the champion CZTSSe solar cell with an efficiency of 12.6%.
J. Conde   +5 more
openaire   +1 more source

Analysis of current conduction mechanism in CZTSSe/n-Si structure

Journal of Materials Science: Materials in Electronics, 2018
In this study, Cu2ZnSn(S,Se)4 (CZTSSe) thin films were deposited by the single step thermal evaporation process using the sintered powder of CZTSSe on soda lime glass (SLG) and Si wafer substrates. The structural, optical, and electrical properties of deposited films were investigated.
Terlemezoğlu, Makbule   +5 more
openaire   +3 more sources

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