Results 61 to 70 of about 45,443 (211)

Structure Elucidation and Total Synthesis of Granolides A–C: Ethyl‐branched Sesquiterpenes From the Tropical Frog Gephyromantis granulatus

open access: yesChemistry – A European Journal, EarlyView.
Males of the tropical frog Gephyromantis granulatus carry unique ethyl‐branched sesquiterpenoid macrolactones in their scent glands. Their structure elucidation was performed by GC/MS, leading to the proposed structures of the granolides. A flexible enantioselective synthesis confirmed the structures and allowed determination of their absolute ...
Johanna Kuhn   +2 more
wiley   +1 more source

Rationales for the Choice of Metals for Super‐Reduced Biological Metal Centers: Cobalt in Cobalamin Versus Nickel in F430

open access: yesChemistry – A European Journal, EarlyView.
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija   +3 more
wiley   +1 more source

Asymptotic properties of cross‐classified sampling designs

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract We investigate the family of cross‐classified sampling designs across an arbitrary number of dimensions. We introduce a variance decomposition that enables the derivation of general asymptotic properties for these designs and the development of straightforward and asymptotically unbiased variance estimators.
Jean Rubin, Guillaume Chauvet
wiley   +1 more source

Derecho al agua en las metrópolis

open access: yesTrayectorias Humanas Trascontinentales
La soberanía nacional, la libertad y la justicia dependen en gran medida de dos agendas públicas prioritarias: la gestión del agua y la seguridad, que se vuelven esenciales para consolidar el sistema político, el régimen institucional y el desarrollo ...
Magdiel GÓMEZ MUÑIZ   +1 more
doaj   +1 more source

La sujétion des médias traditionnels aux dispositifs mobiles de publication : Le cas des applications sur smartphone

open access: yesInterfaces Numériques, 2018
Poussées par l’évolution des usages, les chaînes historiques de télévision ont engagé depuis 2009 la publication de leurs applications sur les smartphones.
Virginie Sonet
doaj   +1 more source

A partial envelope approach for modelling multivariate spatial‐temporal data

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract In the new era of big data, modelling multivariate spatial‐temporal data is a challenging task due to both the high dimensionality of the features and complex associations among the responses across different locations and time points.
Reisa Widjaja   +3 more
wiley   +1 more source

Detecting communities when order and direction matter in social network analysis

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract A novel algorithm combining both node degree and edge betweenness (node degree+edge betweenness) is developed to highlight gradients in connectivity. It identifies communities within complex directed graphs. These are networks that are composed of actors who have ties that originate and end at themselves (self‐loops).
Benjamin Smith, Tyler Pittman, Wei Xu
wiley   +1 more source

Hôtellerie et développement régional : Réflexions autour de paradoxes

open access: yesTéoros, 2004
Textes et études abondent pour traiter de la place que tient l’hôtellerie dans le tourisme et l’économie, entre autres pour analyser les métiers et les moyens à mettre en œuvre afin d’assurer la meilleure formation possible du personnel, pour évaluer la ...
Normand Cazelais
doaj  

Using Financial and Sustainability Ratios to Map Sectors. An Approach With Compositional Data

open access: yesCorporate Social Responsibility and Environmental Management, EarlyView.
ABSTRACT The article aims to visualize in a single graph Spanish fish and meat processing companies with respect to solvency, energy, waste and water intensity and gender employment gap. These financial, environmental, and social indicators are ratios, which require specific statistical analysis methods.
Elena Rondós‐Casas   +3 more
wiley   +1 more source

Desserte ferroviaire à grande vitesse et tourisme

open access: yesTéoros, 2013
À partir d’une revue de la littérature grise (rapports, etc.) et théorique pluridisciplinaire (économie, géographie, aménagement), relative aux interactions entre desserte ferroviaire à grande vitesse et tourisme, cet article vise à présenter un cadre ...
Sylvie Bazin-Benoît, Marie Delaplace
doaj  

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