Results 31 to 40 of about 11,073 (221)

Anaerobic Dechlorinating Bacteria

open access: yesBiotechnology Progress, 1998
AbstractAnaerobic dehalogenation is attracting great interest since it opens new research horizons based on the novel biochemical mechanisms identified in this field such as halorespiration, i.e. the utilization of halogenated compounds as electron acceptors.
El Fantroussi, Saïd   +2 more
openaire   +2 more sources

Vacuum‐Induced Surface Reconstruction of Mn–Ce Oxides for Low‐Temperature Coupled Redox Catalysis

open access: yesAngewandte Chemie, EarlyView.
Near‐surface reconstruction enhances low‐temperature redox catalysis in Mn–Ce mixed oxides. Sequential vacuum annealing and reduced‐pressure O2 treatment enrich Mn near the surface while preserving the CeO2 fluorite framework, promoting interfacial electron redistribution, oxygen activation, and redox cycling.
Yong Yin   +5 more
wiley   +2 more sources

Electro‐Organic Synthesis at a Stable Oil/Water/Solid Three‐Phase Interface Reactor

open access: yesAngewandte Chemie, EarlyView.
A porous membrane electrode (PME) reactor is developed to promote oil/water/solid three‐phase interfacial contact for electro‐organic synthesis. By promoting the formation of an oil/water interfacial region within or near an amphiphilic catalytic layer, the reactor enables efficient conversion of water‐insoluble organic reactants in aqueous ...
Deyin Chen   +7 more
wiley   +2 more sources

Agostic Hydridoborate Complexes as Masked Coinage‐Metal Hydrides: Hydride Migration Between Boron and Gold Unlocks CO2 Reactivity

open access: yesAngewandte Chemie, EarlyView.
Hydride addition to coinage‐metal diphosphine–borane complexes gives unprecedented Cu(I), Ag(I), and Au(I) hydridoborates featuring agostic σ(B–H)→M interactions. While, Cu and Ag derivatives are inert toward CO2, the Au analogue reversibly fixes CO2 and catalyzes its hydroboration as well as formic acid dehydrogenation through a cooperative B─H─Au ...
Balakrishna Peddi   +4 more
wiley   +2 more sources

Preparation of Polyaniline/Polypyrrole Thin Films as Electrode in Salt Water Dechlorination

open access: yesChemistry and Materials, 2022
Chlorine is a chemical element that is widely used in daily life that require for dechlorination process to prevent the environment. One method that can be used to treat chlorine waste is through dechlorination.
Maryanti, Yusmaniar
doaj  

Bioelectrochemical Chlorinated Aliphatic Hydrocarbons Reduction in Synthetic and Real Contaminated Groundwaters

open access: yesChemical Engineering Transactions, 2022
The widespread contamination of chlorinated aliphatic hydrocarbons (CAHs) as Perchloroethylene (PCE) and Trichloroethylene (TCE) over the past recent years and their uncorrected disposal and storing brought these substances to become one of the most ...
Edoardo Dell'Armi   +4 more
doaj   +1 more source

Role of Graphene Oxide in the Nucleation and Growth of Gold Nanoparticles Revealed by Operando Time‐Resolved Studies

open access: yesAngewandte Chemie, EarlyView.
Graphene oxide accelerates AuCl4− reduction under irradiation and directs edge‐selective nucleation and quasi‐one‐dimensional organization of gold nanoparticles at oxygen‐rich boundaries. Operando SAXS and UV–vis spectroscopy, supported by pulse radiolysis and DFT, reveal how progressive conversion of GO to rGO removes interfacial constraints, shifting
Liran Hu   +9 more
wiley   +2 more sources

Reductive Dechlorination of 1,1,2,2-Tetrachloroethane [PDF]

open access: yesEnvironmental Science & Technology, 2002
Products of the transformation of organic pollutants in the environment are often predicted based on the structure of the parent compounds. In some cases, however, multiple products may result from the same reaction pathway. In this study, the reduction of 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA) is investigated both experimentally and computationally.
William A, Arnold   +2 more
openaire   +2 more sources

Stimulated reductive dechlorination-optimization of micron-scale substrate addition [PDF]

open access: yes, 2006
Poster presentation concerned with the stimulated reductive dechlorination-optimization of micron-scale substrate ...
Glew, N.D.   +4 more
core   +4 more sources

Effects of humic electron mediators on reductive dechlorination of polychlorinated biphenyl by consortia enriched from terrestrial and marine environments

open access: yesFrontiers in Microbiology
Humic electron mediators can facilitate the reductive dehalogenation of organohalogenated compounds by accelerating electron transfer. To investigate the effect of humic electron mediators on the microbial anaerobic reductive dechlorination of ...
Qiong Wang   +12 more
doaj   +1 more source

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