Results 11 to 20 of about 46 (42)

Toward Transition-Metal-Templated Construction of Arylated B₄ Chains by Dihydroborane Dehydrocoupling. [PDF]

Chemistry, 2019
Daisy chains of boron: Reactions of dihydroboranes with [(Cp*Ru)2(μ‐H)4] led to complexes arising from differing extents of hydrogen loss, including mono‐ and dinuclear trihydroborate complexes, bridging borylene complexes, and a dinuclear complex bearing a tetraarylated B4 unit.
Lenczyk C, Roy DK, Oberdorf K, Nitsch J, Dewhurst RD, Radacki K, Halet JF, Marder TB, Bickelhaupt M, Braunschweig H.   +9 more
europepmc   +2 more sources

Charge Makes a Difference: Molecular Ionic Bismuth Compounds

Angewandte Chemie, Volume 135, Issue 24, June 12, 2023., 2023
Charged molecular bismuth species encompass cationic and anionic complexes with organic and inorganic ligand spheres as well as ligand‐free molecular clusters. This review provides an overview of their syntheses, structures, and bonding modes. It outlines how the heavy metal bismuth, with its capability of forming non‐toxic compounds, can be understood
Johanna Heine, Benjamin Peerless, Stefanie Dehnen, Crispin Lichtenberg   +3 more
wiley   +2 more sources

Controlled cluster expansion at a Zintl cluster surface

Angewandte Chemie, Volume 136, Issue 3, January 15, 2024.
The stepwise growth of eleven‐ and twelve‐vertex multimetallic clusters from a ten‐atom precursor is demonstrated. These rare examples of closo‐ to closo‐ cluster expansion reactions offer insight into the mechanisms by which Zintl clusters assemble in solution.
Oliver P. E. Townrow, Andrew S. Weller, Jose M. Goicoechea   +2 more
wiley   +2 more sources

Formation of Large Ordered Helium Solvation Shells Around Multiply Charged Species: HeNHo2+ and HeNBi2+

Small Structures, Volume 6, Issue 9, September 2025.
Large ordered structures solvating metallic dications species: A combined experimental and theoretical investigation of HeNHo2+ and HeNBi2+ In this article, the results of a combined experimental and theoretical investigation which provides evidence of the existence of large well‐ordered structures of helium atoms in HeNHo2+ and HeNBi2+ clusters.
Florian Foitzik, Massimiliano Bartolomei, José Campos‐Martínez, Fernando Pirani, Stefan Bergmeister, Lisa Ganner, Ianessa Stromberg, Fabio Zappa, Masoomeh Mahmoodi‐Darian, Tomás González‐Lezana, Elisabeth Gruber   +10 more
wiley   +1 more source

Delocalization‐ratio analysis of 3‐center bonding in position‐space for closo‐boranes and related systems: Approaching the styx picture and beyond

Journal of Computational Chemistry, Volume 45, Issue 32, Page 2862-2877, December 15, 2024.
The Wade's rules and Lipscomb's styx approach constitute a conceptual basis of chemical bonding in closo hydroborane clusters and similar compounds. Based on 3‐center electron sharing indices obtained from DFT wavefunctions, the DR approach for analysis of multicenter bonding in clusters and intermetallic compounds is presented.
Frank R. Wagner
wiley   +1 more source

Ex Situ Reconstruction-Shaped Ir/CoO/Perovskite Heterojunction for Boosted Water Oxidation Reaction. [PDF]

ACS Catal, 2023
Guo H, Yang Y, Yang G, Cao X, Yan N, Li Z, Chen E, Tang L, Peng M, Shi L, Xie S, Tao H, Xu C, Zhu Y, Fu X, Pan Y, Chen N, Lin J, Tu X, Shao Z, Sun Y.   +20 more
europepmc   +1 more source

Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals. [PDF]

Molecules, 2020
King RB.
europepmc   +1 more source

Direct Write of 3D Nanoscale Mesh Objects with Platinum Precursor via Focused Helium Ion Beam Induced Deposition. [PDF]

Micromachines (Basel), 2020
Belianinov A, Burch MJ, Ievlev A, Kim S, Stanford MG, Mahady K, Lewis BB, Fowlkes JD, Rack PD, Ovchinnikova OS.   +9 more
europepmc   +1 more source

φ-Aromaticity in prismatic {Bi₆}-based clusters. [PDF]

Nat Chem, 2023
Peerless B, Schmidt A, Franzke YJ, Dehnen S.   +3 more
europepmc   +1 more source

A review of defect engineering, ion implantation, and nanofabrication using the helium ion microscope. [PDF]

Beilstein J Nanotechnol, 2021
Allen FI.
europepmc   +1 more source