Results 81 to 90 of about 21,930 (288)

Metal‐free deoxygenation of α‐hydroxy carbonyl compounds and beyond

, 2019
Efficient deoxygenation methods are needed now more than ever in the chemist's toolbox to convert biomass‐derived molecules such as carbohydrates into useful chemicals. Late‐stage deoxygenation of drug candidates constitutes also an interesting option to
Pichon, Maeva, Compain, Philippe, Hazelard, Damien, Philippe Compain, Damien Hazelard, Maëva M. Pichon   +5 more
core   +1 more source

CO2‐Driven Synthesis of Holey Edge‐Carboxylated Graphene for Tunable Electronic Interactions in Cu–CeO2‐Catalyzed Water‐Gas Shift Reaction

Carbon Energy, EarlyView.
Holey‐structured, edge‐carboxylated graphene with a controlled specific surface area was synthesized using an environmentally friendly, CO2‐activated, KOH‐free ball‐milling process. ABSTRACT Graphene, notable for its high specific surface area, is ideal for catalyst support but faces challenges under harsh thermal catalytic conditions.
Seon‐Yong Ahn, I‐Jeong Jeon, Won‐Jun Jang, In‐Yup Jeon, Jae‐Oh Shim, Hyun‐Seog Roh   +5 more
wiley   +1 more source

Fe Atoms Accelerator Coupled With Oxygen Vacancies Channel Synergistically Boost OER Performance of Fe‐CoMoO4‐Ov Nanosheets

Carbon Energy, EarlyView.
Fe‐CoMoO4‐Ov/NF demonstrates significantly improved OER catalytic performance compared to CoMoO4. Specifically, the introduced Fe atoms act as a promoter for surface reconstruction, significantly reducing the energy required for surface reconstruction to generate FeCoOOH. The oxygen vacancies serve as electron channels between the core Fe‐CoMoO4‐Ov and
Chaojie Lyu, Jiarun Cheng, Yanhui Yu, Xinlong Tian, Yiming Liu   +4 more
wiley   +1 more source

Novel Deoxygenation Reaction of Epoxides by Indium

, 2016
A novel, mild, ecofriendly protocol for the deoxygenation of epoxides to alkenes using indium metal and indium(I) chloride or ammonium chloride in alcohol has been developed.
John A. Murphy (1266417), Mohan Mahesh (1287006), Hans Peter Wessel (2683222)   +2 more
core   +1 more source

Precision Synthesis of Biomass‐Derived Graphene‐Like Carbon With Tailored Crystallinity via Controlled Flash Joule Heating

Carbon Energy, EarlyView.
A dual‐phase flash Joule heating strategy converts pre‐pyrolyzed biomass into structurally tunable carbon materials from waste feedstocks. By decoupling current‐driven thermodynamic input and duration‐dependent kinetic relaxation, the process maps the transition from amorphous carbon to few‐layer turbostratic graphene and turbostratic nanographite ...
Jiawen Zeng, Yichen Dong, Niyuan Zhu, Danchen Zhu, Hao Jiang, Yingquan Chen, Tong Han, Yonggang Yao, Hanping Chen, Haiping Yang   +9 more
wiley   +1 more source

Preconversion catalytic deoxygenation of phenolic functional groups [PDF]

, 1991
The deoxygenation of phenols is a conceptually simple, but unusually difficult chemical transformation to achieve. Aryl carbon-oxygen bond cleavage is a chemical transformation of importance in coal liquefaction and the upgrading of coal liquids as well ...
Kubiak, C.P.
core   +1 more source

Regulating Interfacial Water Structure on CoNi/MoN Heterostructures Boosts Electrocatalytic Nitrate Reduction to Ammonia

Carbon Energy, EarlyView.
The CoNi/MoN interface effect induces electron transfer from CoNi species to MoN nanosheets, in which electron‐enriched CoNi/MoN interface captures K+ to form K+‐H2O, facilitating H2O dissociation to provide *H for accelerating hydrogenation steps, while electron‐deficient CoNi nanoparticles enhances the NO3− adsorption and reduces the free energy ...
Xue Chen, Jianhui Yi, Guopeng Ding, Zixuan Feng, Qianling Wei, Chunyu Sui, Liqiang Zhang, Zhili Wang, Qing Jiang   +8 more
wiley   +1 more source

Competing effects of wind and buoyancy forcing on ocean oxygen trends in recent decades

Nature Communications
Ocean deoxygenation is becoming a major stressor for marine ecosystems due to anthropogenic climate change. Two major pathways through which climate change affects ocean oxygen are changes in wind fields and changes in air-sea heat and freshwater fluxes.
Helene A. L. Hollitzer, Lavinia Patara, Jens Terhaar, Andreas Oschlies   +3 more
doaj   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

Chemistry – A European Journal, EarlyView.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik, Borys B. Palianytsia, Mykola M. Ilchenko, Nataliia S. Nastasiienko, David J. Morgan, Liudmila P. Storozhuk, David J. Willock, Greg Shaw, Duncan F. Wass, Rafael Luque, Philip R. Davies, Mykola T. Kartel   +11 more
wiley   +1 more source

Additive impacts of deoxygenation and acidification threaten marine biota

, 2020
Deoxygenation in coastal and open-ocean ecosystems rarely exists in isolation but occurs concomitantly with acidification. Here, we first combine meta-data of experimental assessments from across the globe to investigate the potential interactive impacts
Shannon G. Klein, Carlos M. Duarte, Steckbauer, Alexandra, Klein, Shannon, Duarte, Carlos M., Alexandra Steckbauer   +5 more
core   +1 more source