Results 131 to 140 of about 55,314 (289)

Calcium‐Mechanochemistry Enabled Ketone Synthesis From Organic Iodides and Carboxylic Acids

Advanced Science, EarlyView.
Mechanochemically generated organocalcium species display unusual chemoselectivity toward carboxylates, enabling direct ketone synthesis without overaddition. Ball milling activates commercial calcium metal under ambient, solvent‐minimized conditions, providing a broad substrate scope, high functional‐group tolerance, and a practical one‐step ...
Mengyao Pei, Zekun Yang, Xueyan Yang, Yufang Yang, Yangyang Shen, Jiemin Wang, Peile Ma, Zezhu Li, Xiaoliang Zheng, Xiaofeng Wei   +9 more
wiley   +1 more source

Two‐Dimensional Layered Materials for Aqueous Zinc‐Ion Batteries: Multifunctional Roles and Mechanistic Insights

Advanced Science, EarlyView.
This overview summarizes versatile 2D layered materials for AZIB anodes, cathodes, separators and electrolytes, illustrating their dendrite/side reaction suppression mechanisms, and analyzes existing hurdles to propose scalable commercial research outlooks.
Shuge Dai, Chenke Yang, Yunrui Jiang, Gaopan Liu, Jianbin Zhou, Ye Wang, Longhui Zeng, Yuen Hong Tsang   +7 more
wiley   +1 more source

Multiscale Modelling of the Electrocatalysis of Microenzymes: Insights Into the Performance of Microperoxidase at an Aqueous/Graphene Interface and Their Exploitation to Improve Performance

Advanced Science, EarlyView.
A novel multiscale MD/DFT framework to elucidate microenzyme adsorption and electron transfer is reported. This method reveals distinct configurations for microperoxidase‐11 on graphene and those best suited for electron transfer. Rate constants align with the limited experimental data, establishing this framework as a tool for optimizing microenzyme ...
Milan Mijajlovic, Cheng Hu, Yuhui Sun, Matthew J. Penna, Meisam V. Kiamahalleh, Wenrong Yang, Mark J. Biggs   +6 more
wiley   +1 more source

Novel perspectives on the mechanism of phosphate conversion coating on magnesium alloys

Results in Surfaces and Interfaces
Chemical conversion coating (CCC) is a cost-effective and industrially scalable technique to tackle the issue of corrosion of Magnesium and its alloys, crucial for reducing global greenhouse gas emissions by the road transportation sector.
Debasis Saran, Anil Daliprasad Pathak, David Klaumünzer, Sivaiah Bathula, Kisor Kumar Sahu   +4 more
doaj   +1 more source

In‐Situ Constructed Cations for 2D/3D Perovskite Heterostructure for Stable and Efficient Photovoltaics

Advanced Science, EarlyView.
An in‐situ spacer‐cation construction strategy is developed by inducing strong hydrogen bonding between n‐hexyl phosphonic acid (HPA) and FA+, forming a stable N‐type 2D/3D perovskite heterostructure. This approach suppressed defect formation, promoted electron transport, and improved intrinsic stability, delivering 26.32% PCE, excellent operational ...
Min Liu, Quanwen You, Licheng Liu, Xinbo Shi, Zhen Wang, Bo Wu, Zhengchi Yang, Guofu Zhou, Jun‐Ming Liu, Jinwei Gao, Yue Jiang   +10 more
wiley   +1 more source

A Bifunctional Organosilane Additive for Dynamic pH Regulation and Interfacial Protection in Aqueous Zinc‐Ion Batteries

Advanced Science, EarlyView.
A novel multifunctional additive for aqueous zinc‐ion battery electrolytes can simultaneously dynamically adjust the pH in microzones, regulate the solvation structure of Zn2+, protect the interface, and form a stable solid‐state SEI film. This approach enables a dendrite‐free zinc anode and demonstrates excellent cycling stability and cycle life ...
Lina Pan, Haiyang Wu, Peng Huang, Boyu Yuan, Chao Lai, Yaqian Lan   +5 more
wiley   +1 more source

Deprotonation–Substitution of N-Boc-tetrahydroisoquinolines [PDF]

, 2017
Tetrahydroisoquinolines (THIQs) are found in a wide range of natural products and compounds with biological activity. This thesis describes the methodology of deprotonation‒substitution as an efficient route to 1-substituted THIQs and 3-substituted THIQs.
Talk, Ruaa
core  

A Phosphorylation‐Induced Micellization Switch in the Low‐Complexity Domain of TDP‐43

Advanced Science, EarlyView.
Phosphorylation of TAR DNA‐binding protein's 43 kDa (TDP‐43) low‐complexity domain by casein kinase 1 delta (CK1δ) acts as a molecular switch, redirecting its self‐assembly from macroscopic phase separation toward finite‐sized, spherical block‐copolymer micelles of ∼30 nm.
Rodrigo F. Dillenburg, Anastasia Lopatina, Hao Ruan, Tom Scheidt, Simone Mosna, Emre Pekbilir, Julia Bieber, Frank Schäfer‐Depoix, Katharina Landfester, Carla Schmidt, Martin M. Möckel, Svenja Morsbach, Friederike Schmid, Dorothee Dormann, Lukas Stelzl, Martin Girard, Edward A. Lemke   +16 more
wiley   +1 more source

Meta-Xylene-Based Diamines with Protected Benzyl Sites: Potential NCN Pincer Ligands with Tunable Steric Profiles

Molecules
Bulky NCN aryl-diamides featuring methyl groups in the benzyl positions were synthesized with the aim of creating a new class of meta-xylene-based trianionic pincer ligands where the common decomposition pathway of metal pincer complexes via C-H ...
Tamina Z. Kirsch, Toren Hynes, Jason D. Masuda, Saurabh S. Chitnis   +3 more
doaj   +1 more source

Harmonizing Rigidity and Flexibility: Embedding COF Quantum Dots Into Extracellular Matrix Gel as Carbon Monoxide Depot for Acoustically Triggered Time‐Programmable Anti‐Infective Therapy

Advanced Science, EarlyView.
A rigid‑flexible integrated CO depot is engineered by embedding rigid COFQDs into a flexible ECM gel network. The rigid framework enables high‑capacity CO storage and sonodynamic bacterial killing, while the flexible ECM gel controls sustained CO release, collectively eradicating multidrug‑resistant infection and promoting scarless healing.
Baohong Sun, Fang Han, Chunxiao Zhu, Zhiyuan Yang, Haoru Wang, Jinpei Mei, Jie Chen, Jingwen Zhu, Zihan Bo, Taju Wu, Xiaogang Zhou, Tao Ma, Yutian Su, Youhui Lin   +13 more
wiley   +1 more source