Catalytic Exchange of Deuterium and Hydrogen in Hydrocarbons [PDF]
L. Farkas, Adalbert Farkas
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Designing Enzymatic Reactivity with an Expanded Palette
Innovation in biocatalysis is rapidly increasingly the diversity of catalytic reactivity that can be mediated by enzymes, addressing a key bottleneck for their widespread adoption in industrial chemical synthesis. A key approach to this is building enzymes with unnatural catalytic components that provide an expanded palette with new possibilities for ...
Reuben B. Leveson‐Gower
wiley +1 more source
Deuterated water (<sup>2</sup>H<sub>2</sub>O, heavy water) labelling to investigate human cell dynamics <i>in vivo</i> - lessons in protocol design and toxicity from the current literature. [PDF]
Song A+4 more
europepmc +1 more source
Exchange Reaction between Deuterium and Ammonia on Synthetic Ammonia Catalysts Promoted Singly, Doubly, and Triply [PDF]
Hiroshi Uchida, Naoyuki Todo
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Selective [9‐15N] Guanosine for Nuclear Magnetic Resonance Studies of Large Ribonucleic Acids
The small chemical shift anisotropy of nitrogen‐15 at the 9‐position in guanine (15N9‐G) leads to long T2 values and narrow NMR lines, particularly attractive to probe structure and dynamics of large (>200 nucleotide) ribonucleic acids (RNAs). RNAs regulate various cellular processes using malleable 3D structures, and understanding the factors that ...
Solomon K. Attionu+5 more
wiley +1 more source
Towards <i>trans</i>-dual deuterated cyclopropanes <i>via</i> photoredox synergistic deuteration with D<sub>2</sub>O. [PDF]
Wu Y+8 more
europepmc +1 more source
Biosynthesis of Ephedrine is Initiated by Pyridoxal Phosphate‐Dependent Formation of Cathinone
Ephedra alkaloids possess some of the most basic structures of alkaloids. Despite their importance for human use and their commercial relevance, the biosynthesis of ephedra alkaloids has remained enigmatic. The predominant biosynthetic pathway in the literature proposes a thiamine‐dependent caboligation followed by a transaminase, although no candidate
Karina Witte+4 more
wiley +1 more source
Real-World Data Confirm That the Integration of Deuterium Depletion into Conventional Cancer Therapy Multiplies the Survival Probability of Patients. [PDF]
Somlyai G+4 more
europepmc +1 more source
Studies of Deuterium Plasma in Heavy Current Linear Pulse Discharges
Katsuhiko Nishiguchi+3 more
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Ru‐Catalyzed Alkene Hydrophosphination: Correlating Substrate Scope with An Outer‐Sphere Mechanism
The rate of this outer‐sphere hydrophosphination catalyzed by a Cp*Ru complexdepends on the speed of either conjugate addition A delicate balance between these two possible turnover‐limiting steps is sensitive to the structure and electronic character of both the alkene and phosphine substrates, with big impacts on activity and selectivity.
Jin Yang+3 more
wiley +1 more source