Results 221 to 230 of about 274,158 (325)

Hydrogen Bonding Network in Interlayer Spaces of a Partially Deuterated Layered α‐Sn (IV) Phosphate: A Solid‐State MAS NMR Study

open access: yesMagnetic Resonance in Chemistry, EarlyView.
The solid‐state 1H and 2H NMR data collected for deuterated α‐Sn (HPO4)2 phosphate suggest the hydrogen bonding network, where the cavity water accepts one hydrogen bond from the P‐OH donor group and forms one hydrogen bond with the neighboring phosphate group, while the other water hydrogen is not involved in hydrogen bonding.
Vladimir I. Bakhmutov, Hong‐Cai Zhou
wiley   +1 more source

Dynamic signature of activity-stability tradeoff in lactamase evolution. [PDF]

open access: yesNat Commun
Arcia E   +9 more
europepmc   +1 more source

Quantification of Homopolymer Impurities in Structured Acrylate Copolymers Produced by High‐Temperature Semi‐Batch Radical Polymerization

open access: yesMacromolecular Reaction Engineering, EarlyView.
Isobornyl acrylate macromonomer solutions are synthesized via high‐temperature radical polymerization using a starved‐feed semi‐batch operating policy. Through sequential feeding, the macromonomer solution functions as an addition‐fragmentation agent, facilitating the production of blocky and comb acrylate copolymers.
Elizabeth G. Bygott   +3 more
wiley   +1 more source

Absolute Quantification of Brain Deuterium Metabolic Imaging in Healthy Volunteers and Glioblastoma Patients at 7T

open access: yesMagnetic Resonance in Medicine, EarlyView.
ABSTRACT Purpose We present a method for absolute quantification of deuterated metabolites in vivo at 7T. We describe acquisition protocols and an analysis pipeline compatible with 7T Terra MRIs. We apply them using a 2H/1H receive array in healthy volunteers and glioblastoma patients.
Jabrane Karkouri   +12 more
wiley   +1 more source

Matching habitat choice could be brightness‐based instead of hue‐based in green‐brown polymorphic grasshoppers

open access: yesOikos, EarlyView.
Some prey species have evolved background matching, that is they resemble their surrounding environment in terms of colour and/or brightness. When prey populations inhabit patchy environments, they may even have evolved specialised phenotypes: each phenotype matching a specific subset of patches.
Lilian Cabon, Holger Schielzeth
wiley   +1 more source

Disarming the Hsp70–Bim Alliance: Small‐Molecule and Peptidic Disruptors of a Chaperone‐Apoptotic Switch in Cancer

open access: yesChemistryOpen, EarlyView.
Targeting a nucleotide‐sensitive groove on Hsp70 that binds the Bim BH3 helix, we integrate structures, biophysics, and SAR from peptides, fragments, and phenalene‐dicarbonitrile “wedges.” These disrupt the Hsp70–Bim complex with sub‐µM cellular engagement and in vivo activity while sparing Hsp90/mortalin.
Emadeldin M. Kamel   +5 more
wiley   +1 more source

Mapping the structural dynamics of red- and blue-emitting beetle luciferases revealed by HDX-MS. [PDF]

open access: yesLife Sci Alliance
Kharbatli AR   +6 more
europepmc   +1 more source

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