Multiplicative Stereocontrol in the Light-Driven Deracemization of Benzylic Nitriles. [PDF]
Du YE +4 more
europepmc +1 more source
NiH‐Catalyzed Enantio‐ and Regioselective Hydroselenylation of Unactivated Alkenes
Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Hyung‐Joon Kang +2 more
wiley +1 more source
Nitrogen Radical Photocatalysed Reduction of Nitrous Oxide. [PDF]
This work offers the first example of reduction of the potent greenhouse gas N2O to the benign products N2 and O(Bpin)2 using a nitrogen‐based catalyst. The active catalyst is shown to be a nitrogen‐based radical which operates under photocatalytic conditions.
Lister-Roberts R, Crumpton AE, Mehta M.
europepmc +3 more sources
Enantioselective hydrogen atom relay via non-covalent catalyst assembly. [PDF]
Yalamanchili N +3 more
europepmc +1 more source
The diphenylphosphinyl radical 1 was investigated under matrix isolation conditions using IR, UV/Vis, and EPR spectroscopy. Solid para‐hydrogen was found to represent a powerful medium to resolve the hyperfine structure of a phosphorus‐centered π radical 1 by EPR spectroscopy.
Mika Maehara +4 more
wiley +1 more source
The essential role of hydrogen gas recycling by gut microbes in reducing deuterium load in host mitochondria: is trimethylamine oxide a deuterium sensor? [PDF]
Seneff S, Boros LG.
europepmc +1 more source
Strain and Chirality: Catalytic Asymmetric Synthesis of Planar Chiral [2.2]Paracyclophanes
Catalytic asymmetric synthesis is transforming access to planar‐chiral [2.2]paracyclophanes. This Review highlights recent advances in catalytic desymmetrization and asymmetric functionalization, emphasizing how catalyst design and PCP geometry govern reactivity and stereocontrol.
Daniel Alonso +2 more
wiley +1 more source
Water-Dispersible Ruthenium Nanocatalyst for Carbonyl Reduction With D<sub>2</sub> or T<sub>2</sub> in Aqueous Media. [PDF]
Martinelli E +6 more
europepmc +1 more source
Abstract Quantitative multiPLEXed Rapid Immunoprecipitation and Mass spectrometry of Endogenous proteins (qPLEX‐RIME) is a method for the quantitative discovery of endogenous protein complexes, without the need for genetically encoded affinity tags. It is particularly well suited to chromatin‐associated proteins and transcription factors, permitting ...
Soleilmane Omarjee +8 more
wiley +1 more source
Cobalt-Catalyzed Reductive Asymmetric Dimerization of 1,3-Enynes: Rapid Synthesis of Enantioenriched Skipped 1,3,6-Trienes. [PDF]
Lin JN, Wei XF, Yu Q, Shu W.
europepmc +1 more source

