Cysteine Thioaldehydes: Photolytic Generation, Reactivity, and Biological Implications
Photolysis of cysteine phenacylsulfides bearing non‐conjugating electron‐withdrawing substituents leads to high conversions into cysteine thioaldehydes through a Norrish type‐II pathway. This methodology enabled the study of the aqueous reactivity of these important biosynthetic intermediates, which, depending on peptide sequence, pH and buffer ...
Ardra Karthika +9 more
wiley +2 more sources
Enhanced nuclear fusion in the sub-keV energy regime. [PDF]
Karahadian ME +4 more
europepmc +1 more source
Genome mining of atypical condensation (C) domains leads to the discovery of myxoglucamides, glycolipopeptides featuring an unprecedented vinyl‐substituted, α‐oxidized γ‐amino acid. Biosynthetic studies reveal a discrete C‐domain‐like O‐acyltransferase, a β‐hydroxylation‐dependent chain‐extension checkpoint, and an unusual pathway for γ‐amino acid ...
Tingting Wang +10 more
wiley +2 more sources
<sup>2</sup>H<sub>2</sub>O labeling methods for bulk and single muscle protein synthesis measures, and measures of integrated muscle protein synthesis and breakdown rates: A pilot study. [PDF]
Højfeldt G +7 more
europepmc +1 more source
High‐Pressure Synthesis of Quantum‐Stabilised Manganese Superhydride MnH7
Superhydrides are a rarity in transition metal hosts. Through high‐pressure, high‐temperature diamond anvil cell studies, the most hydrogen‐rich transition metal hydride, MnH7${\rm MnH}_7$ has been synthesised. Density functional theory calculations demonstrate that zero‐point energy stabilises the crystalline structure that MnH7${\rm MnH}_7$ adopts ...
Mikhail A. Kuzovnikov +10 more
wiley +2 more sources
Molecular dynamics of deuterium plasma on TiB₂ sputtering in tokamak wall surfaces for Shannon entropy of computation. [PDF]
Pahsa A.
europepmc +1 more source
Explaining deuterium-depleted water as a cancer therapy: a narrative review. [PDF]
Kyriakopoulos AM, Seneff S.
europepmc +1 more source
Trapping the Excess Electron of FeB-Type CeSi by Hydrogenation ─ Formation of Ferromagnetic Hydrides CeSiHx (TC ≈ 24 K). [PDF]
Dorsch LY +9 more
europepmc +1 more source
Development of an inhibitory monoclonal nanobody targeting Streptococcus pyogenes siderophore binding protein FtsB. [PDF]
Fernandez-Perez J +9 more
europepmc +1 more source

