Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
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Regulation of the histone H3K36 methyltransferase Set2 by the histone chaperone Spt6. [PDF]
Elchert AR +5 more
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Karl Popper and the Mechanisms of Hydrogen Embrittlement
Representation of the beginning of loss of ductility rather than embrittlement. Small concentrations of hydrogen in a diffusible form within iron are well‐established to harm the mechanical integrity of steels. There are theories that attempt to explain the pernicious role of hydrogen.
H. K. D. H. Bhadeshia
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Radiolabeling of oligopeptides by selective hydrogen isotope exchange with deuterium and tritium in aqueous buffers. [PDF]
Martinelli E +3 more
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Nickel-catalyzed asymmetric hydrogenation of α,β-unsaturated ester phosphonates. [PDF]
Wei H +7 more
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Water as a Sustainable Hydrogen Donor in Transfer Hydrogenation and Reduction Reactions. [PDF]
Ponnam D, Chen J, Fan B.
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First Evidence for Ozonido‐TMC Complexes of Iron and Cobalt
Reaction of ozone with iron(II) complexes [(TMC)Fe(OTf)]BArF, [(D12‐TMC)Fe(OTf)]BArF, and cobalt(II) complexes [(TMC)Co(OTf)]BArF, [(D12‐TMC)Co(X)]BArF (X = OTf, F) gives ozonido and oxido complexes at temperatures as low as –155°C in a 4:1 mixture of 2‐Me‐THF and THF. ABSTRACT We present compelling evidence for the first Fe‐ and Co‐ozonido complexes: [
Stefan Schaub +14 more
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Detection of regional metabolic alteration using 7T deuterium metabolic imaging in MRI-negative, <sup>18</sup>FDG-PET-positive epilepsy patients. [PDF]
Ahmadian N +9 more
europepmc +1 more source
Protocol to measure protein half-life in cell culture using heavy water. [PDF]
Alamillo L +5 more
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