Results 211 to 220 of about 273,322 (239)

Equilibrium-driven decarbonylative multi-deuteration enables access to highly deuterated carbon frameworks. [PDF]

Chem Sci
Lee J, Park T, Park JE, Moon HW, Lee S.
europepmc   +1 more source

Amide‐Enabled Reversal of Regioselectivity in Carbonyl‐Substituted Allenes

Advanced Synthesis &Catalysis, Volume 368, Issue 20, 16 October 2026.
A substrate‐embedded secondary amide reverses the inherent regioselectivity of carbonyl‐substituted allenes, enabling rhodium‐catalyzed α‐acyloxylation with carboxylic acids. This redox‐neutral method requires no external oxidants or auxiliary‐type directing groups and tolerates diverse carboxylic acids.
Naoki Hikida, Keita Obata, Yasuharu Yoshimi, Hirotsugu Suzuki   +3 more
wiley   +1 more source

Mechanistic Insights into the Photodegradation of Trityl Radicals. [PDF]

Org Lett
Shibata A, Abe M.
europepmc   +1 more source

Photocatalyst‐Free Hydrodifluoromethylation of Alkenes via Thiol‐Mediated Photoactivation of Zn(CF2H)2(DMPU)2

Advanced Synthesis &Catalysis, Volume 368, Issue 20, 16 October 2026.
Herein, we report a photocatalyst‐free hydrodifluoromethylation of alkenes using Zn(CF2H)2(DMPU)2 and thiophenols under 390 nm irradiation. The thiophenol serves a dual stoichiometric function, promoting the formation of a photoactive thiol‐modified organozinc species while acting as the terminal hydrogen‐atom donor.
Hyunsu Kim, Seonyoung Kim, Hyunwoo Kim
wiley   +1 more source

Ruthenium-Catalyzed Nitrile-Acrylate Reductive Coupling by 2-Propanol: Synthesis of Enantioenriched β-Amino Esters. [PDF]

Angew Chem Int Ed Engl
Höthker S, Hayter CE, Shen W, Krische MJ.   +3 more
europepmc   +1 more source

Wireless Electrochemical Palladium Membrane Reactor

ChemElectroChem, Volume 13, Issue 20, 16 October 2026.
A wireless palladium membrane reactor is developed and characterized. The advantage of this architecture is demonstrated through its application in the lithium‐mediated nitrogen reduction reaction, where an external hydrogen supply does not need to be provided.
Hossein Bemana, Jost Heise, Shuai Yan, Hariprasad Ranganathan, Abolfazl Kiani, Nikolay Kornienko   +5 more
wiley   +1 more source

Radiolabeling of oligopeptides by selective hydrogen isotope exchange with deuterium and tritium in aqueous buffers. [PDF]

Nat Commun
Martinelli E, Weck R, Güssregen S, Derdau V.   +3 more
europepmc   +1 more source

A Computational Model for Determining Labeling Duration in Protein Turnover Studies Using a Single Deuterated Water Labeled Sample. [PDF]

J Am Soc Mass Spectrom
Deberneh HM, Sadygov RG.
europepmc   +1 more source

Manganese-pyridone-catalyzed site-selective hydrogen isotope exchange of 2-arylpyridines using D₂O. [PDF]

RSC Adv
Bai JF, Qian T, Yao Y, Jiang ZJ, Chen J, Gao Z.   +5 more
europepmc   +1 more source

Carboxyl-directed, general α-site-selective deuteration of carboxylic acids by Pd₁/CeO_x single-atom catalyst. [PDF]

Nat Commun
Su J, Min XT, Huang Y, Fang X, Zhang WT, Jiang X, Yu B, Jiang W, Pan X, Li L, Qiao B, Wang A, Zhang T.   +12 more
europepmc   +1 more source