Results 81 to 90 of about 273,322 (239)

Mechanism of an Alcohol-Trapping Reaction in the Direct and Benzophenone-Sensitized Photodenitrogenation of a Spiroepoxy-Substituted Azoalkane:  Solvent Effects and Stereochemical Deuterium Labeling

, 2016
The spin-state-dependent reactivity, singlet versus triplet, of the 2-spiroepoxy-1,3-cyclopentane-1,3-diyl DR2 has been assessed through alcohol-trapping reactions for which the effect of solvent acidity on the product distribution of the alcohol ...
Yasunori Ino (2122015), Waldemar Adam (1392745), Masatomo Nojima (2016028), Manabu Abe (362853), Takafumi Minamoto (3034293)   +4 more
core   +2 more sources

Hydration‐Gated Photoinduced Electron Transfer in BODIPY Dyes

Angewandte Chemie, EarlyView.
Hydration switches photoinduced electron transfer (PET) ON in alkoxy‐coordinated BODIPY dyes via specific hydrogen bonding. This gating yields a fluorescence lifetime span of ∼6 ns, enabling fluorescence lifetime imaging microscopy (FLIM) contrast in live cells and organoids. ABSTRACT Fluorescent probes based on photoinduced electron transfer (PET) are
Venkata N. K. Mamillapalli, Irina A. Okkelman, Fatima Akhssas, Greta Sambucari, Angela C. Debruyne, Dinesh Beniwal, Christophe Bucher, Mariangela Di Donato, Ruslan I. Dmitriev, Mikhail A. Filatov   +9 more
wiley   +2 more sources

Synthesis of Melamine-d6 and the Feasibility of Deuterium Labeled Compounds as Internal Standard

Journal of Isotopes, 2015
S-triazine is an important chemical intermediate. Melamine belongs to s-triazine, which has been widely used as an additive in the food industry. To study the stable isotope labeling method of heterocyclic triazine compounds and its application, one step
GUO Yang-zhen, REN Jing-xia, NING Jun, MEI Xiang-dong   +3 more
doaj   +1 more source

Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling

, 2003
Mormann M, Kuck D. Hydride abstraction from 1,3,5-cycloheptatriene by gaseous carbenium ions, as studied by Fourier transform ion cyclotron resonance kinetics and deuterium labeling. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY.
Mormann, Michael, Dietmar Kuck, Kuck, Dietmar, Michael Mormann   +3 more
core   +1 more source

CeO2‐Based Electrocatalysts for the Oxygen Evolution Reaction: Design, Dynamic Mechanisms, and Electrolyte Adaptability

Advanced Science, EarlyView.
This Review shows how cerium oxide helps water‐splitting catalysts work better and last longer. It explains how CeO2 tunes electronic structure, oxygen‐vacancy behavior, and surface reconstruction, while adapting to alkaline, acidic, and seawater conditions.
Zhen Cui, Ailing Song, Zirui Cui, Manman Duanmu, Zhipeng Ma, Hao Liu, Guangjie Shao, Xinyi Tan, Guoxiu Wang, Hao Tian   +9 more
wiley   +1 more source

A Mild Disilane‐Enabled Halide‐to‐Deuterium Manifold With D2O for Aryl and Benzylic Halides

Angewandte Chemie, EarlyView.
A broadly applicable Pd‐catalyzed dehalogenative deuteration enables efficient conversion of aryl and benzylic halides with inexpensive deuterium oxide (D2O). The method proceeds under exceptionally mild conditions without strong bases, harsh reductants, or stoichiometric Lewis acid halide scavengers, and tolerates a wide range of functional groups ...
Wenliang Wang, Ryan Parlett, Liam Hornstein, Landon Conklin, Qi Tang, Xiaodong Shi   +5 more
wiley   +2 more sources

Analysis of sesquiterpene hydrocarbons in grape berry exocarp (Vitis vinifera L.) using in vivo-labeling and comprehensive two-dimensional gas chromatography–mass spectrometry (GC×GC–MS)

Beilstein Journal of Organic Chemistry, 2019
Sesquiterpenes are structurally diverse, potent flavoring substances that significantly influence the aroma profile of grapes (Vitis vinifera L.) at the time of physiological ripening.
Philipp P. Könen, Matthias Wüst
doaj   +1 more source

Deciphering Electrochemical Generation, Transport, and Reactivity of Hydrogen Species in the Electrochemical Palladium Membrane Reactor

Advanced Science, EarlyView.
This study elucidates hydrogen transport and reaction mechanisms in ePMR using 1‐hexyne hydrogenation as a model reaction. Hydrogen transport operates via dual pathways involving hydrogen atom permeation and H2‐mediated re‐dissociation on secondary metal layers.
Samuel J. Shin, Su Bin Roh, Hyun‐Tak Kim, Kwan‐Young Lee, Soo Min Kim, Ji Hoon Park, Minju Park   +6 more
wiley   +1 more source

Structure and Biosynthesis of Mangotoxin Produced by the Plant Pathogen Pseudomonas syringae

Angewandte Chemie, EarlyView.
The structure of mangotoxin remained elusive for over two decades. Here, mangotoxin was isolated from the native producer, Pseudomonas syringae pv. syringae, and was determined to be an alkyne‐containing dipeptide. Mangotoxin inhibited the growth of multidrug‐resistant human pathogen Klebsiella pneumoniae.
Alexis H. Murray, Sohan Hazra, Ryan W. Mull, Erinn M. O'Neill, Bo Li   +4 more
wiley   +2 more sources

Multiscale Regulation of Ru‐Based Catalysts for Upgrading Biomass‐Derived Levulinic Acid and Levulinates to γ‐Valerolactone: Mechanisms, Advances, and Challenges

Advanced Science, EarlyView.
This review summarizes recent advances in the mechanistic, thermodynamic, and kinetic studies of biomass‐derived levulinic acid/levulinates conversion to γ‐valerolactone, along with the corresponding multiscale regulation strategies of Ru‐based catalysts.
Xin Ni, Cailu Xiao, Gongbing Zhou, Jingzi Zhang   +3 more
wiley   +1 more source