Results 151 to 160 of about 946,755 (288)

An Ambient Photocatalytic Approach to In‐Situ Prepare Cobalt/Cobalt Phosphide and Cobalt/Cobalt Phosphide@Graphene Heterojunction Nanomaterials With Optimized Charge Separation Effects for Highly Efficient Relayed Electrocatalytic NOX− Reduction to NH3

open access: yesCarbon Energy, EarlyView.
A visible‐light‐driven ambient photocatalytic method in‐situ fabricates Co/CoP‐x and Co/CoP@rGO heterojunction with enhanced charge separation, enabling highly efficient relayed electrocatalytic NOx− reduction to NH3 with outstanding Faraday efficiency and ammonia productivity.
Xin Zhao   +7 more
wiley   +1 more source

One‐Shot Pd(II)‐Catalyzed Multiple C–H Activation Enables Modular Construction of Fluorenylidene Oxindole‐Based Multi(Polycyclic) Aromatic Enes

open access: yesChemistry – A European Journal, EarlyView.
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang   +4 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

N─H or O─H Bond Activation With a Bicyclic Si4 Ring Compound

open access: yesChemistry – A European Journal, EarlyView.
The bicyclic Si4 ring compound with zwitterionic character reacts with NH3, H2O, and selected alcohols to give functionalized saturated silicon rings, siliconoid clusters with unsubstituted Si atoms, or simple 1,3‐addition products. The experimentally observed reactivity could be rationalized based on results from mechanistic calculations employing ...
Michael Quest   +7 more
wiley   +1 more source

Is exclusive breastfeeding an option or a necessity in Africa? A pooled study using the deuterium oxide dose-to-mother technique. [PDF]

open access: yesJ Public Health Afr, 2020
Mulol H   +6 more
europepmc   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

open access: yesChemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz   +6 more
wiley   +1 more source

Silver‐Mediated Deuterium Labelling of Quinones and Related Compounds by Hydrogen Isotope Exchange With D2O

open access: yesChemistry – A European Journal, EarlyView.
A new silver‐catalyzed H/D exchange reaction was developed for the labelling of quinones and related compounds. Both homogeneous and heterogeneous catalytic processes were implemented using heavy water as a simple deuterium source. The corresponding deuterated compounds were obtained with high isotopic enrichment through a practical method that opens ...
Joyce C. de Oliveira   +7 more
wiley   +1 more source

Deuterium-L-DOPA : a novel means to improve treatment of Parkinson's disease

open access: yes, 2012
L-DOPA, the precursor of dopamine, is administered to restore dopamine deficiency in Parkinson´s disease (PD) patients. L-DOPA initially provides a sustained symptomatic relief with superior efficacy as compared to other treatments, while long term ...
Torun Malmlof (18676393)
core   +1 more source

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