Results 41 to 50 of about 64,299 (292)

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

open access: yesAngewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +2 more sources

The Ecology and Palaeoecology of Diatom – Duckweed Relationships [PDF]

open access: yes, 2015
This thesis focuses on the ecology and palaeoecology of diatom-duckweed relationships and utilises a combined experimental, ecological and palaeoecological approach.
Emson, D
core  

Dental Microwear Texture Analysis on Radular Teeth

open access: yesAdvanced Materials Interfaces, EarlyView.
3D microwear textures reveal how gastropod radular teeth respond to controlled abrasive contact. Distinct surface signatures distinguish regular abrasion from fracture‐dominated material removal, showing how mineralized coatings, fibrous cores, and substrate properties jointly shape wear and failure in a biological scraping interface.
Wencke Krings   +2 more
wiley   +1 more source

[O─I─O]+ Halogen‐Bonded Complexes of Pyridine N‐Oxides

open access: yesAngewandte Chemie, EarlyView.
The missing puzzle of 3‐center‐4‐electron halogen‐bonded complexes viz. [O─I─O]+ of pyridine N‐oxides are structurally characterized by x‐ray diffraction. Monodentate N‐oxide O‐atom acts as the halogen bond acceptor. Their solution complexations are characterized by 15N NMR spectroscopy.
Rakesh Puttreddy   +3 more
wiley   +2 more sources

The use of diatom records to establish reference conditions for UK lakes subject to eutrophication [PDF]

open access: yes, 2011
A knowledge of pre-disturbance conditions is important for setting realistic restoration targets for lakes. For European waters this is now a requirement of the European Council Water Framework Directive where ecological status must be assessed based on ...
Bennion, H, Simpson, GL
core  

An Examination of the Cs2NaInCl6 Luminescence: Interplay of Self‐Generated In+ and Doped Sb3+, Er3+/Yb3+ Ions

open access: yesAdvanced Optical Materials, EarlyView.
A new luminescence mechanism in Cs2NaInCl₆ is revealed through spontaneously formed In3+→In+ centers and Er3+/Yb3+/Sb3+ doping. Tunable visible, near‐infrared, downconversion, and upconversion emissions are demonstrated, while DFT calculations explain the electronic structure.
Inna A. Ivashchenko   +10 more
wiley   +1 more source

Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex

open access: yesAngewandte Chemie, EarlyView.
We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer   +6 more
wiley   +2 more sources

Experimental Study on Hypochlorous Acid Blocking the Marine Diatom Adhesion

open access: yesInternational Journal of Electrochemical Science, 2012
We investigated the effect of hypochlorous acid (HOCl) on biofouling diatom adhesion by using sea-water antifouling electrolysis method. Results revealed that the diatom killing effect of HOCl generated by electrolysis device was positively correlated ...
Shuangkou Chen   +4 more
doaj   +1 more source

High‐Throughput Screening and Interpretable Machine Learning for Rational Design of Bimetallic Catalysts for Methane Activation

open access: yesAdvanced Science, EarlyView.
ABSTRACT Methane's efficient catalytic removal is vital for sustainable development. Bimetallic catalysts, though promising for methane activation, pose a design challenge due to their complex compositional space. This work introduces an integrated framework that combines high‐throughput density functional theory (DFT) and interpretable machine ...
Mingzhang Pan   +8 more
wiley   +1 more source

Reconstruction of Holocene sea-levels using diatom- and pollen-based microfossil transfer functions, west coast of Scotland, UK [PDF]

open access: yes, 2007
Due to its sensitivity to isostatic and eustatic sea-level change the west coast of Scotland has been an important area for studying sea-level change. Recently, data from north west Scotland have been used to refine GIA models because of the presence of ...
Gregory, Caroline
core  

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