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Angewandte Chemie, 1985
Die stabilen Doppelbindungsisomere 1 und 1′ waren eine der Überraschungen, die die wenig untersuchten 1,5‐Diazocine zu bieten haben. Von anders substituierten Verbindungen dieser Klasse liegt, soweit geprüft, jeweils nur ein Isomer mit fixierten Doppelbindungen vor.
Christoph Schnieders +3 more
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Die stabilen Doppelbindungsisomere 1 und 1′ waren eine der Überraschungen, die die wenig untersuchten 1,5‐Diazocine zu bieten haben. Von anders substituierten Verbindungen dieser Klasse liegt, soweit geprüft, jeweils nur ein Isomer mit fixierten Doppelbindungen vor.
Christoph Schnieders +3 more
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1,2-Diazocines,1,3-Diazocines,Triazocines,and Tetrazocines
ChemInform, 1990Publisher Summary This chapter discusses the eight-membered heterocycles containing (a) two nitrogens, (b) three nitrogens, and (c) four nitrogens. In this chapter, all the compounds are classified according to the actual relationship of the eight-membered ring nitrogens to each other, regardless of formal nomenclature.
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Cross-Coupling Strategy for the Synthesis of Diazocines
Organic Letters, 2020Ethylene bridged azobenzenes are novel, promising molecular switches that are thermodynamically more stable in the (Z) than in the (E) configuration, contrary to the linear azobenzene. However, their previous synthetic routes were often not general, and yields were poorly reproducible, and sometimes very low.
Shuo Li, Nadi Eleya, Anne Staubitz
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Synthetic strategies and diversification of dibenzo[1,5]diazocines
Organic & Biomolecular Chemistry, 2023Recent synthetic approaches and functionalisation of dibenzo[1,5]diazocines, epiminodibenzo[1,5]diazocines and epoxydibenzo[1,5]diazocines are reviewed.
Abdul Qaiyum Ramle, Edward R. T. Tiekink
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Diazocines on Molecular Platforms
European Journal of Organic Chemistry, 2014AbstractNew diazocines as photochromic switches for the surface functionalization via the “platform approach” were synthesized and characterized. Symmetric diazocines as well as asymmetric molecules based on an indane scaffold were obtained and their photochromic properties were investigated.
Tobias Tellkamp +3 more
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Simple formation of a diazocine ring
Journal of the Chemical Society D: Chemical Communications, 19711,3-Diaminopropane reacts with benzylidene–acetone to give an eight-membered ring in high yield.
K�lm�n Hideg, Douglas Lloyd
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ChemInform Abstract: 1,5‐Diazocine.
Chemischer Informationsdienst, 1985AbstractDas Diazasemibullvalen (Ia) lagert sich beim Erhitzen in das entsprechende 1,5‐Diazocin um, welches in Form der beiden nicht trennbaren Doppelbindungsisomeren (II) und (III) vorliegt.
C. SCHNIEDERS +3 more
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1989
Publisher Summary This chapter covers eight-member rings containing two nitrogens in a 1,4 position, and their fused-ring analogs. In some respects, the nomenclature of 1,4-diazocines is similar to that for the eight-member ring containing one nitrogen.
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Publisher Summary This chapter covers eight-member rings containing two nitrogens in a 1,4 position, and their fused-ring analogs. In some respects, the nomenclature of 1,4-diazocines is similar to that for the eight-member ring containing one nitrogen.
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Synthesis of 1,5-diazocin-2-ones
Russian Chemical Bulletin, 2021This review is focused on the synthetic approaches to the eight-membered nitrogen heterocycles, 1,5-diazocin-2-ones, exhibiting promising biological activities. Nomenclature of these compounds is considered and the examples of the natural and pharmacologically important compounds of the 1,5-diazocin-2-one family are given.
J. P. Matheny, A. V. Aksenov, M. Rubin
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