Results 151 to 160 of about 44,278 (213)

A Scalable Synthesis of a New Quasi‐Reversible Redox Compound with a High Positive Redox Potential

open access: yesChemElectroChem, EarlyView.
A new redox active molecule with an extraordinary high redox potential of +1.45 V vs standard hydrogen electrode (SHE) is found. To elucidate the electrochemical redox mechanism of the 1,4‐diallyl‐2,5‐bis(allyloxy)benzene a series of model compounds was developed and electrochemically characterised.
Rune Kjærgaard Groven   +4 more
wiley   +1 more source

The Electrochemical Shono Oxidation of N‐Formylpyrrolidine: Mechanistic Insights from the Computational Ferrocene Electrode Model and Cyclic Voltammetry

open access: yesChemElectroChem, EarlyView.
The mechanism of Shono oxidation is studied by combining cyclic voltammetry, a computational ferrocene reference electrode, and density functional theory. The study identified the role of proton‐coupled electron transfer in the oxidation pathway. The approach allows for the calculation of both electron and proton transfer, as well as their coupled ...
Liana Savintseva   +5 more
wiley   +1 more source

Performance‐Conscious Coadditive Approach for Enhancing Proton Exchange Membrane Durability: Roles of Tungsten Oxides and Cerium Ions

open access: yesChemElectroChem, EarlyView.
Simultaneous incorporation of tungsten oxide (WOx) and cerium (Ce) ions into proton exchange membranes (PEMs) enhances their chemical durability while imposing minimal penalties on fuel cell performance. WOx decomposes hydrogen peroxide, while Ce ions scavenge hydroxyl radicals. Their complementary functions, combined with the immobility of WOx, enable
Kazuma Shinozaki   +8 more
wiley   +1 more source

Ensemble‐based soil liquefaction assessment: Leveraging CPT data for enhanced predictions

open access: yesCivil Engineering Design, Volume 7, Issue 1, Page 23-35, March 2025.
Abstract This study focuses on predicting soil liquefaction, a critical phenomenon that can significantly impact the stability and safety of structures during seismic events. Accurate liquefaction assessment is vital for geotechnical engineering, as it informs the design and mitigation strategies needed to safeguard infrastructure and reduce the risk ...
Arsham Moayedi Far, Masoud Zare
wiley   +1 more source

Synergistic Molecular Engineering Strategies for Enhancing Diffusion Kinetics and Interfacial Stability of the δ‐MnO2 Cathode in Aqueous Zinc‐Ion Batteries

open access: yesCarbon Energy, EarlyView.
We developed a δ‐MnO2@2‐ML cathode material for aqueous zinc‐ion batteries, utilizing 2‐ML interlayer modulation and interface engineering, that not only increases the layer spacing and promotes the diffusion of Zn2+, but also stabilizes the surface Mn sites and inhibits the dissolution of Mn.
Yaxi Ding   +12 more
wiley   +1 more source

Crown Ether Supported Alkali Metal Phosphides: Synthesis, Structures and Bonding

open access: yesChemistry – A European Journal, EarlyView.
Crowned! Herein we describe a complete series of crown ether coordinated alkali metal phosphides from lithium to cesium, including solid state structures, detailed investigations in solution and extensive quantum chemical investigation of the bonding situation.
Felix Krämer   +5 more
wiley   +1 more source

Harnessing Synergies between Combinatorial Microfluidics and Machine Learning for Chemistry, Biology, and Fluidic Design

open access: yesChemistry–Methods, EarlyView.
This review explores the synergy of combinatorial microfluidics and machine learning, highlighting their transformative impact on high‐throughput experimentation, closed‐loop reaction optimization, and autonomous platform development. Key applications in chemical synthesis, biological research, and microfluidic design are discussed, addressing ...
Suyash S. Damir   +3 more
wiley   +1 more source

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