Results 91 to 100 of about 37,517 (252)

Characteristic Conformation of Mosher’s Amide Elucidated Using the Cambridge Structural Database

open access: yesMolecules, 2015
Conformations of the crystalline 3,3,3-trifluoro-2-methoxy-2-phenylpropanamide derivatives (MTPA amides) deposited in the Cambridge Structural Database (CSD) were examined statistically as Racid-enantiomers. The majority of dihedral angles (48/58, ca. 83%
Akio Ichikawa, Hiroshi Ono, Yuji Mikata
doaj   +1 more source

Toward a Rational Design of Conjugated Copolymers with Oxygenated Side Chains for Boosting Thermoelectric Properties

open access: yesAdvanced Energy Materials, EarlyView.
The molecular design strategy that integrates both side chain and backbone engineering in diketopyrrolopyrrole‐based conjugated polymers to identify the optimal balance between doping efficiency and microstructural order is demonstrated. Comprehensive spectroscopic, electrochemical, morphological, and structural characterizations reveal that the ...
Taewoong Han   +13 more
wiley   +1 more source

T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond

open access: yesAngewandte Chemie, EarlyView.
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag   +4 more
wiley   +2 more sources

Methyl 9-diethylamino-2,2-bis(4-methoxyphenyl)-2H-benzo[h]chromene-5-carboxylate

open access: yesActa Crystallographica Section E, 2011
In the title compound, C31H29NO5, the methyl carboxylate and dimethylamino groups on the naphthopyran group are almost coplanar with the naphthopyran ring system [r.m.s.
Moon-Hwan Kim   +2 more
doaj   +1 more source

Weak automorphisms of dihedral groups [PDF]

open access: yesAlgebra universalis, 2010
Let \(G\) be a group; a bijective map \(\tau\colon G\to G\) is called a weak automorphism of \(G\) if for every \(n\in\mathbb N\), every \(g_1,g_2,\dots,g_n\in G\) and every \(\alpha_1,\alpha_2,\dots,\alpha_n\in\mathbb Z\) there are \(\beta_1,\beta_2,\dots,\beta_n\in\mathbb Z\) such that \[ \tau(g_1^{\alpha_1}\cdot g_2^{\alpha_2}\cdots g_n^{\alpha_n})=\
openaire   +1 more source

Rational Backbone Planarization for Doping‐Resilient Polymeric Hole Transport Materials Toward Stable and Scalable Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
Incorporating divinylbenzene into PTAA‐based copolymers induces backbone planarization and promotes polaron delocalization, leading to enhanced doping resilience and stabilized electronic structure. The resulting hole‐transport material, PDVB14, maintains robust performance under high dopant concentrations and prolonged device operation, offering a ...
Chanhyeok Kim   +10 more
wiley   +1 more source

Structural Control of Dual Emission in Coumarin Fluorophores for Visualizing Protein Droplet Maturation

open access: yesAngewandte Chemie, EarlyView.
A coumarin‐based dual‐emission fluorophore was designed to visualize the maturation of protein liquid droplets. Upon covalent conjugation to droplet‐forming proteins, ratiometric fluorescence imaging allowed real time monitoring of droplet maturation. This probe is applicable to the analysis of droplet formation and maturation mechanisms, as well as to
Tomoya Yamamoto   +6 more
wiley   +2 more sources

[2,7-Dimethoxy-8-(4-propylbenzoyl)naphthalen-1-yl](4-propylphenyl)methanone

open access: yesActa Crystallographica Section E, 2012
In the title compound, C32H32O4, the 4-propylbenzoyl groups at the 1- and 8-positions of the naphthalene ring system are aligned almost antiparallel, and their benzene rings make a dihedral angle of 8.64 (10)°.
Kosuke Sasagawa   +4 more
doaj   +1 more source

On the class groups of dihedral groups

open access: yesJournal of Algebra, 1980
Let A be a Z-order in a semisimple Q-algebra -4. Let C(A) denote the class group of A defined by using locally free left A-modules. Define D(d) to be the kernel of the natural map C(A) + C(Q) for Q a maximal Z-order in A containing A and d(A) to be the order of D(d).
Endo, Shizuo, Miyata, Takehiko
openaire   +2 more sources

Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals

open access: yesAngewandte Chemie, EarlyView.
Competing homotypic and heterotypic intermolecular interactions give rise to polymorphic structure–property dynamics in luminescent molecular crystals. Thermal and mechanical stimuli induce distinct phase‐transition pathways accompanied by pronounced photoluminescence changes.
Mahiro Nakabayashi, Shotaro Hayashi
wiley   +2 more sources

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