Results 161 to 170 of about 37,517 (252)

Planarized and Twisted Intramolecular Charge Transfer: Small Geometric, Huge Photophysical Changes

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Molecular motion governs excited state relaxation in aminobenzonitrile donor–acceptor systems. Small structural modifications control single and dual rotations and enable distinct relaxation pathways. Fluorescence spectroscopy, Lippert–Mataga analysis, and theoretical calculations identify multiple excited states, including a dual‐emitting planarized ...
Zoe Nonie Scheller   +2 more
wiley   +1 more source

Role of Central Arene Rotators and Ag<sup><b>+</b></sup>, I<sup><b>+</b></sup>, and PdCl<sub>2</sub> Centers in Hexagonal Macrocycles as Molecular Rotors. [PDF]

open access: yesInorg Chem
Litts NP   +9 more
europepmc   +1 more source

Spirobifluorene fusion in multiple resonance frameworks enables efficient pure‐red OLEDs with narrowband emission and suppressed efficiency roll‐off

open access: yesFlexMat, EarlyView.
An orthogonal spirobifluorene‐fusion strategy is introduced for B/N/O‐alternated MR frameworks, enabling improved kRISC (5.46 × 103 s−1), high ΦPL (97%), and narrow‐band pure‐red emission. Vacuum‐evaporated OLEDs incorporating this emitter achieve an EQEmax >40% (FWHM = 36 nm) and exhibit exceptionally low efficiency roll‐off at high luminance ...
Yan‐Yun Jing   +7 more
wiley   +1 more source

Heteroatom location‐ and orientation mode‐dependent reverse intersystem crossing rate in multiple resonance emitters

open access: yesFlexMat, EarlyView.
By constructing two pairs of isomers with different heteroatom anchoring positions, the relationship between heteroatom location and orientation mode and reverse intersystem crossing rate constant (kRISC) in multiple resonance (MR) emitters is systematically investigated.
Tingting Huang   +5 more
wiley   +1 more source

Tokenizing loops of antibodies. [PDF]

open access: yesMAbs
Fang A   +3 more
europepmc   +1 more source

Carbonyl lock enables multi‐resonant organoboron framework with substantially enhanced spin‐flip and reduced emission bandwidth

open access: yesFlexMat, EarlyView.
Integrating carbonyl lock onto multi‐resonant organoboron emitters is found to go beyond conventional bridge unit. It can not only suppress the molecular relaxation as conventional bridge, but also substantially affect electronic engineering via carbonyl integration, activating multiple up‐conversion channels, thus leading to an accelerated spin‐flip ...
Tingfeng Chen   +7 more
wiley   +1 more source

Deep red to near‐infrared thermally activated delayed fluorescence conjugated polymers toward highly efficient solution‐processible deep red and near‐infrared organic light‐emitting diodes

open access: yesFlexMat, EarlyView.
A series of deep red (DR) and near‐infrared (NIR) thermally activated delayed fluorescence conjugated polymers are prepared, their solution‐processible organic light‐emitting diodes exhibit DR emission with maximum external quantum efficiency (EQEmax) of 6.4%, high luminance of 4254 cd m−2 and emission peak at 678 nm, and a NIR device with EQEmax of 2 ...
Tao Wang   +5 more
wiley   +1 more source

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