Point-to-volume engineering enables enhanced birefringence and a wide bandgap in hybrid halide ultraviolet nonlinear optical crystals. [PDF]
Wu J, Li RN, Yao WD, Fu YF, Guo SP.
europepmc +1 more source
Abstract The crania of leporid lagomorphs are uniquely fenestrated, including the posterior cranial bones and the lateral portion of the maxilla. The functional significance of the highly fenestrated rostrum has received considerably little attention, despite being absent in other mammalian herbivores with a long rostrum.
Amber P. Wood‐Bailey, Alana C. Sharp
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Molecular Origins of the Optical Response of Nile Red in Model Aerosol Aqueous Ionic Environments. [PDF]
Boadu M +6 more
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The mechanism of labor in nonhuman primates: A look inside
Abstract While in humans, the flexed position of the fetus and its rotating course down the birth canal are well documented, in other primates the mechanism of labor is unknown. Despite the lack of comparative data, it is commonly assumed that the human obstetric mechanism is unique, and anthropologists have disputed when and why the transition to the ...
Melissa K. Stoller
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Asymmetric Xanthene with Noncovalent Conformation Locks to Attain High Fluorescence >1500 nm. [PDF]
Chowdhury P +12 more
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Metal‐Ion Regulated Light‐Free Z→E Isomerization of Azobenzene Glycomacrocycle
Metal ion‐catalyzed Z→E isomerization of photoswitchable azobenzene glycomacrocycle: A new azobenzene‐based glycomacrocycle is capable of forming a 1:1 complex with divalent metal ions in both E‐ and Z‐isomers. The complexes undergo light‐free Z→E isomerization in a timescale spanning from seconds to weeks.
Yang Zhou +4 more
wiley +1 more source
Fluorination of alkoxide ligands: neither too much, nor too little for optimal ligand field strength. [PDF]
de Zwart FJ +4 more
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A comprehensive experimental and theoretical study is presented of a family of TADF dyes. Comparing the behavior of structurally related dyes, we uncover the subtle and somewhat unexpected role of conformational degrees of freedom associated with peripheral groups that affect the delicate interplay of excited states that governs spin–orbit coupling ...
Andrea Landi +7 more
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Substrate-Specific Differences in Catalytic Strategy and Activity across Ketol-Acid Reductoisomerase Variants. [PDF]
Karvelis E, Tidor B.
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Interplay of Bridge Topology and Conformation in Phenylene‐Bridged Trityl Diradicals
We present a meta‐phenylene‐bridged trityl diradical that exhibits an unexpectedly weak antiferromagnetic exchange coupling J with a strong environment‐dependent magnitude. Combined VSM, EPR, DFT, and MD studies reveal that structural flexibility modulates σ‐, π‐, and through‐space exchange contributions, highlighting the crucial role of geometry in ...
Kevin Lars Kopp +4 more
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